Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Rainer Balles"'
Publikováno v:
Nachrichten aus der Chemie. 56:368-371
Publikováno v:
Zeitschrift für Naturforschung B. 39:445-448
C6H2Cl3NO2, the hitherto unknown intermediate in the preparation of 2,5-diamino-3,6-dichloro-1,4-benzoquinone by ammonolysis of chloranil, the mono-substituted title compound, was obtained in 18% yield. It crystallizes in the orthorhombic space group
Autor:
Bernhard Powietzka, Basil Kanellakopulos, Rainer Balles, Gerd Becker, Helmut Schmidt, Bernd Nuber, Manfred L. Ziegler
Publikováno v:
ChemInform. 18
The title compound 1 is the complex of a novel ligand. It is formed from [(CH3C5H4)Mn(CO)2·thf] and (CH3)3C-C=P, presumably with uptake of H2O. The bis(phosphavinyl) ether in 1 functions as an 8-electron donor toward the four (CH3C5H4)Mn(CO)2 units
Autor:
Bernhard Powietzka, Rainer Balles, Helmut Schmidt, Gerd Becker, Manfred L. Ziegler, Basil Kanellakopulos, Bernd Nuber
Publikováno v:
Angewandte Chemie. 99:929-930
Der Komplex eines neuartigen Liganden ist die Titelverbindung 1. Sie entsteht aus [(CH3C5H4)Mn(CO)2·thf] und (CH3)3C-C=P vermutlich unter H2O-Aufnahme. Im paramagnetischen Komplex 1 fungiert der Bis(phosphavinyl)ether als 8-Elektronendonor gegenuber
Autor:
Gerd Becker, Bernhard Powietzka, Basil Kanellakopulos, Helmut Schmidt, Bernd Nuber, Manfred L. Ziegler, Rainer Balles
Publikováno v:
Angewandte Chemie International Edition in English. 26:900-901
The title compound 1 is the complex of a novel ligand. It is formed from [(CH3C5H4)Mn(CO)2·thf] and (CH3)3C-C=P, presumably with uptake of H2O. The bis(phosphavinyl) ether in 1 functions as an 8-electron donor toward the four (CH3C5H4)Mn(CO)2 units