Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Raghavakaimal Padmakumar"'
Publikováno v:
Biochemistry. 38:15278-15286
Taurine/alpha-ketoglutarate dioxygenase (TauD), a member of the broad class of non-heme Fe(II) oxygenases, converts taurine (2-aminoethanesulfonate) to sulfite and aminoacetaldehyde while decomposing alpha-ketoglutarate (alphaKG) to form succinate an
Publikováno v:
Tetrahedron Letters. 39:5151-5154
Zeolite supported zinc borohydride is a versatile catalyst for the regeoselective reduction of epoxides, conjugated ketones, and aldehydes to the corresponding alcohols in good yields.
Publikováno v:
Synthetic Communications. 28:2071-2075
A convenient method for the synthesis of various azafluorenones (2a-f & 4a-d) by cyclization of substituted arylpyridines (1a-f & 3a-d) using zeolites are described.
Autor:
Raghavakaimal Padmakumar, R. Sreekumar
Publikováno v:
Synthetic Communications. 28:1661-1665
A convenient heterogeneous catalytic methodology for the synthesis of Pyrroles and Pyrazoles by an intermolecular reaction of γ or β-diketones with primary amines or hydrazine derivatives over zeolites are described.
Publikováno v:
Inorganica Chimica Acta. 270:392-398
The Co-C stretching vibration has been identified in resonance Raman spectra of alkyl-cobalamins, via isotope substitution, permitting estimation of the Co-C force constants, f = 1.85, 1.77 and 1.50 mdyn A−1 for methyl-, ethyl- and deoxyadenosyl-co
Publikováno v:
Tetrahedron Letters. 38:6557-6560
Zeolites, an environmentally attractive solid catalyst, proves to be an efficient catalyst for Michael addition of several 1, 3-dicarbonyl compounds and thiols as donors with methyl vinyl ketone, acrolein and methyl acrylate as acceptors without any
Autor:
Raghavakaimal Padmakumar, R. Sreekumar
Publikováno v:
Tetrahedron Letters. 38:5143-5146
Potassium permanganate supported on zeolite can be used for the selective oxidation of various enamines, alkylarenes and unsaturated alcohols to the corresponding ketones, in good yield. Arenes were selectively oxidized at the benzylic position. If t
Publikováno v:
Tetrahedron Letters. 38:3179-3182
A novel heterogeneous catalytic method to synthesize various heterocyclic compounds of biological interest, aminobenzisothiazole [2a-h] and 1,3-thiazine derivatives [4, 6] , using an environmentally attractive solid catalyst, zeolite, is described.
Autor:
Raghavakaimal Padmakumar, R. Sreekumar
Publikováno v:
Tetrahedron Letters. 38:2413-2416
S-Allyl γ-hydroxy ketene dithioacetals [ 1a–1e ] underwent a rapid and diastereoselective thio-Claisen rearrangement into anti α-allyl β-hydroxy dithioesters [ 2a–2e ] over various zeolites at room temperature in hexane is described. © 1997 E
Autor:
R. Sreekumar, Raghavakaimal Padmakumar
Publikováno v:
Synthetic Communications. 27:777-780
A convenient heterogeneous catalytic methodology for Friedel-Crafts acylation of benzene and toluene using various aliphatic carboxylic anhydrides over zeolites at 250 °C is described. An interesting para selectivity is observed in the case of acyla