Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Rafael Schiwon"'
Publikováno v:
Journal of Organometallic Chemistry. 821:71-77
The reaction of [Fp]2 (Fp = (η5-C5H5)(CO)2Fe) with bismuth formate was shown to proceed via Fe-Bi bond formation yielding [Fp–Bi(O2CH)2]n, 1, that could be crystallized in form of two polymorphs. These differ in the way the [Fp−Bi(O2CH)2] units
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 642:1198-1206
While addition of [Cp2ReH] to [Bi(OtBu)3] leads to an equilibrium containing [Cp2Re-Bi(OtBu)2], [{Cp2Re}2Bi(OtBu)], tBuOH and [CpRe(μ-η5,η1-C5H4)Bi–ReCp2], in the presence of water [{(Cp2Re)2Bi}2O] (1) is formed selectively. Also [FpH] [Fp = (η
Autor:
Thomas Happe, Matthias Driess, Kajsa G.V. Sigfridsson, Shenglai Yao, Christian Limberg, Nils Leidel, Rafael Schiwon, Michael Haumann, Annika Brünje, Petko Chernev, Ramona Kositzki, Camilla Lambertz, Chung-Hung Hsieh
Publikováno v:
Inorganic Chemistry. 53:12164-12177
[FeFe]-hydrogenase from green algae (HydA1) is the most efficient hydrogen (H2) producing enzyme in nature and of prime interest for (bio)technology. Its active site is a unique six-iron center (H-cluster) composed of a cubane cluster, [4Fe4S]H, cyst
Publikováno v:
Zeitschrift für Naturforschung B. 68:561-568
Reaction of equimolar amounts of [Bi(OtBu)3] and [Cp2ReH] yields [Cp2Re-Bi(OtBu)2], 1, when the reaction time is kept short. Treatment of [Bi{OCH(CF3)2}3(thf)]2 with four equivalents of [Cp2ReH] leads to the heterotrinuclear complex [(Cp2Re)2Bi{OCH(C
Autor:
Soma Salamon, Heiko Wende, Ulrich Hagemann, Joachim Landers, Georg Bendt, Rafael Schiwon, Christian Limberg, Stephan Schulz
Publikováno v:
Inorganic chemistry. 55(15)
Nearly phase-pure bismuth ferrite particles were formed by thermolysis of the single-source precursor [Cp(CO)2FeBi(OAc)2] (1) in octadecene at 245 °C, followed by subsequent calcination at 600 °C for 3 h. In contrast, the slightly modified compound
Publikováno v:
Organometallics. 29:1670-1674
The reaction of rhenocene hydride with bismuth alkoxides leads to complexes containing Re−Bi metal bonds with concomitant formation of the corresponding alcohols. Hence, compounds of the type [Cp2R...
Publikováno v:
Chemical communications (Cambridge, England). 50(1)
Modification of the Co-oxo cores of cobalt-polyoxometalate water oxidation catalysts is detectable by X-ray absorption spectroscopy (XAS) as demonstrated by comparison of Na10[Co4(H2O)2(PW9O34)2] (1) and Na17[((Co(H2O))Co2PW9O34)2(PW6O26)] (2). XAS r
Autor:
Sidabras, Jason W.1 (AUTHOR) jwsidabras@mcw.edu, Stripp, Sven T.2 (AUTHOR) sven.stripp@gmail.com
Publikováno v:
Journal of Biological Inorganic Chemistry (JBIC). Jun2023, Vol. 28 Issue 4, p355-378. 24p.
Autor:
Schiwon, Rafael1, Braun, Beatrice1, Metzinger, Ramona1, Limberg, Christian1 christian.limberg@chemie.hu‐berlin.de
Publikováno v:
Zeitschrift für Anorganische und Allgemeine Chemie. Oct2016, Vol. 642 Issue 21, p1198-1206. 9p.
Publikováno v:
Chemical Communications; 2014, Vol. 50 Issue 1, p100-102, 3p