Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Rachel E. McIlwaine"'
Publikováno v:
The Journal of Physical Chemistry C. 112:2499-2505
Experimental results are presented of an acid autocatalytic reaction (the bromate-sulfite clock reaction) performed in water-in-oil (w/o) microemulsions with neutral (Triton X-100, TX) or cationic (CTAB) surfactants. The characteristics of the pH-sen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::be896b5f906d4baf4f14ce0d716e7616
https://doi.org/10.1021/jp076238s
https://doi.org/10.1021/jp076238s
Publikováno v:
Chemical Physics Letters. 417:39-42
The formaldehyde–sulfite reaction is an acid to alkali clock reaction in batch, which displays complex behaviour in a flow reactor. Current published mechanisms do not account for the behaviour in an open system. In this Letter, we construct a mini
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5237c5a1c463324262e864ffa3922b86
https://doi.org/10.1016/j.cplett.2005.09.116
https://doi.org/10.1016/j.cplett.2005.09.116
Publikováno v:
Physical chemistry chemical physics : PCCP. 9(28)
The Methylene Glycol-Sulfite-Gluconolactone (MGSG) reaction is the first example of an organic-based pH oscillator. This reaction is of particular interest as it displays large amplitude oscillations in hydroxide ion accompanied by small amplitude (1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c686a8914a6c3bf1fcaa71f1762594f0
https://pubmed.ncbi.nlm.nih.gov/17622405
https://pubmed.ncbi.nlm.nih.gov/17622405
Publikováno v:
The journal of physical chemistry. A. 111(4)
In a recent paper, we suggested that the acid- or base-catalyzed dehydration of a hydrated carbonyl compound provides a suitable foundation for an organic-based pH oscillator. Here we present the first experimental example of such an oscillator in a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::15cda8db6bdcee6b2cc4c0506da1b2bd
https://pubmed.ncbi.nlm.nih.gov/17249741
https://pubmed.ncbi.nlm.nih.gov/17249741
Publikováno v:
The journal of physical chemistry. A. 109(1)
The formaldehyde-sulfite reaction is an example of an "acid-to-alkali" clock. It displays an induction period, during which the pH varies only slowly in time, followed by a reaction event, during which the pH increases rapidly by several units. When
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cd70596cf05133144573442dda4d0819
https://pubmed.ncbi.nlm.nih.gov/16839118
https://pubmed.ncbi.nlm.nih.gov/16839118
Publikováno v:
Physical Chemistry Chemical Physics (PCCP); Jul2007, Vol. 9 Issue 28, p3711-3716, 6p
Publikováno v:
Journal of Physical Chemistry A; Feb2007, Vol. 111 Issue 4, p549-551, 3p