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Autor:
Sriganesh B. Sharma, Rachel A. Byerly, Björn C.G. Söderberg, Matthew M. Cummings, Ronald W. Clawson, Novruz G. Akhmedov
Publikováno v:
Tetrahedron. 67:4753-4757
An expedient synthesis of the alkaloid salviadione, the only to date isolated naturally occurring 1H-benzo[def]carbazole is described. The key step in the synthesis is a palladium-catalyzed, carbon monoxide-mediated reductive N-heterocyclization of a