Zobrazeno 1 - 10
of 71
pro vyhledávání: '"R.M. Lequan"'
Publikováno v:
Synthetic Metals. 42:1663-1666
Conducting organometallic salts based on tetracyanoquinodimethane (TCNQ) and metallocenes of iron, (Cp)Fe(Ar), where the metal is complexed by two rings: cyclopentadienyl (Cp) and substituted benzen ring (Ar), have been synthesized with the following
Publikováno v:
J. Chem. Soc., Faraday Trans.. 87:2225-2228
The synthesis of {4′-[methyl(diphenyl)phosphonio]biphenyl-4-yl}triphenylborate (PBB) and 4′-(diphenylphosphino)biphenyl-4-yl(methyl)diphenylphosphonium hexafluorophosphate (PBP) is described. The properties of PBP and PBB are investigated by abso
Autor:
Jean-Philippe Bourgoin, Michel Vandevyver, R.M. Lequan, Annie Ruaudel-Teixier, A. Barraud, M. Lequan, M. Roulliay
Publikováno v:
Journal of Physics D: Applied Physics. 23:987-990
A new strategy for building conducting LB films is presented. The conducting behaviour is obtained by mixing in the same layer amphiphilic and semi-amphiphilic TCNQ derivatives. The optimum conductivity (6.9*10-3 S cm-1) is obtained for hybrid stacks
Autor:
M Lequan, R.M Lequan
Publikováno v:
Tetrahedron Letters. 22:1323-1326
Resume Optically active tetraorganotin compounds have been synthesized by reaction of organometallic reagents on a tin cinchoninate intermediate at low temperature.
Publikováno v:
Electrochimica Acta. 30:455-459
The electrochemical reduction of tetracyanoquinodimethane (TCNQ) has been studied in acetonitrile solutions containing different diphosphonium cations (D2+). In each case a solid compound, the composition of which corresponds to DTCNQ4, has been isol
Publikováno v:
Synthetic Metals. 27:257-262
Single crystal X-ray diffraction, ESR and electrical conductance were studied to clarify both the magnetic and transport properties on a radical-anion salt of ternary compound, Me 3 S + ( I 3 − ) 1 3 TCNQ − 2 3 with respect to the role of the I3
Publikováno v:
Organic Magnetic Resonance. 7:392-400
All J(PH) and J(PC) values, including signs, have been obtained in acetylenic and propynylic phosphorus derivatives, R2P(X)CCH and R2P(X)CCCH3 (X oxygen, lone pair and R C6H5, N(CH3)2, OC2H5, N(C6H5)2, Cl) from 1H and 13C NMR spectra. In PIV derivati
Publikováno v:
Synthetic Metals. 10:415-425
The structural and conducting properties of two 1:4 charge transfer disphosphonium-TCNQ salts, prepared by reaction of the corresponding iodides with TCNQ in hot acetonitrile, are compared. The diphosphonium-paraphenylene (DPPP 2+ salt resembles the
Publikováno v:
Synthetic Metals. 19:409-414
A new series of semi-conducting organo-metallic salts derived from tetrathiafulvalene (TTF) has been prepared by the electro-oxidation technique: (TTF) (MnCl3−)−0.75 ( σ RT ⋍ 15 Ω −1 cm −1 ), ( TTF ) ( MnCl 4 −− ) ⋍0.25 ( σ RT ⋍
Autor:
Pierre Delhaes, C. Garrigou-Lagrange, S.A. Rózański, M. Kurmoo, M. Lequan, F.L. Pratt, R.M. Lequan, G. Maceno
Publikováno v:
Solid State Communications. 67:481-485
A new class of radical-cation has been investigated: (TTF)14(MCl4)4 where M = Co, Mn, Zn. These compounds crystallize in a monoclinic system with two sets of orthogonal triads in a crystallographic plane. D.c. electrical conductivity measurements exh