The effect of alkylation on the micro-solvation of ethers revealed by highly localized water librational motion

Autor: D. Mihrin, A. Voute, P. W. Jakobsen, K. L. Feilberg, R. Wugt Larsen

Publikováno v: Mihrin, D, Voute, A, Jakobsen, P W, Feilberg, K L & Larsen, R W 2022, ' The effect of alkylation on the micro-solvation of ethers revealed by highly localized water librational motion ', The Journal of Chemical Physics, vol. 156, no. 8, 084305 . https://doi.org/10.1063/5.0081161

The specific far-infrared spectral signatures associated with highly localized large-amplitude out-of-plane librational motion of water molecules have recently been demonstrated to provide sensitive spectroscopic probes for the micro-solvation of org

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d0abc81c14405db368f9ef1746ce00d6
https://pubmed.ncbi.nlm.nih.gov/35232174

High-resolution infrared and ab initio investigation of CHD279Br: Ro-vibrational analysis of the ν6 fundamental and the 2ν6−ν6 hot band

Autor: D. De Vito, Agostino Baldacci, Paolo Stoppa, R. Wugt Larsen, Santi Giorgianni, Alberto Gambi

The high-resolution infrared spectrum of CHD2 79Br has been investigated by Fourier transform spectroscopy in the range 540–615 cm−1 at an unapodised resolution of 0.0035 cm−1. This spectral region...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a565b41dff73173ca9e167ff36acd385
http://hdl.handle.net/10278/3728069

Far-Infrared Investigation of the Benzene-Water Complex: The Identification of Large-Amplitude Motion and Tunneling Pathways

Autor: Bengt Nelander, Justinas Ceponkus, Per Uvdal, R. Wugt Larsen, Johannes Andersen

Publikováno v: The journal of physical chemistry. A. 124(3)

The far-infrared spectrum of the weakly OH···π hydrogen-bonded benzene-water complex has been studied in neon and argon matrices, below 30 K. The in-plane water libration has been observed in both neon and argon for H2O and D2O complexed with C6H

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::72a4d8079e0e83e6c7433b2e9f1ce509
https://pubmed.ncbi.nlm.nih.gov/31815483

Highly localized H

Autor: D, Mihrin, J, Andersen, P W, Jakobsen, R, Wugt Larsen

Publikováno v: Physical chemistry chemical physics : PCCP. 21(4)

The most prominent spectroscopic observable for the hydrogen bonding between individual molecules in liquid water is the broad absorption band detected in the spectral region between 300 and 900 cm-1. The present work demonstrates how the associated

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https://pubmed.ncbi.nlm.nih.gov/30623967

High‐Resolution Infrared Synchrotron Investigation of (HCN)2 and a Semi‐Experimental Determination of the Dissociation Energy D0

Autor: Dmytro Mihrin, Laurent Manceron, R. Wugt Larsen, P. W. Jakobsen, A. Voute

Publikováno v: ChemPhysChem
ChemPhysChem, Wiley-VCH Verlag, 2019, 20 (23), pp.3238-3244. ⟨10.1002/cphc.201900811⟩
Chemphyschem
Mihrin, D, Jakobsen, P W, Voute, A P, Manceron, L & Wugt Larsen, R 2019, ' High-Resolution Infrared Synchrotron Investigation of (HCN) 2 and a Semi-Experimental Determination of the Dissociation Energy D 0 ', ChemPhysChem, vol. 20, no. 23, pp. 3238-3244 . https://doi.org/10.1002/cphc.201900811

The high‐resolution infrared absorption spectrum of the donor bending fundamental band ν 61 of the homodimer (HCN)2 has been collected by long‐path static gas‐phase Fourier transform spectroscopy at 207 K employing the highly brilliant 2.75 Ge

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aa69da52472b5cf9b303fc280f2dc471