Zobrazeno 1 - 10
of 137
pro vyhledávání: '"R. Verlet"'
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-8 (2024)
Abstract The hydrated electron, e– (aq), has attracted much attention as a central species in radiation chemistry. However, much less is known about e– (aq) at the water/air surface, despite its fundamental role in electron transfer processes at
Externí odkaz:
https://doaj.org/article/e78b7bb4f6034f5b810d31ba02e1f5ef
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-1 (2024)
Externí odkaz:
https://doaj.org/article/ddf19009872e40f9b9523a991a95dcb5
Autor:
Alejandra Guillén-García, Savannah E. R. Gibson, Caleb J. C. Jordan, Venkata K. Ramaswamy, Victoria L. Linthwaite, Elizabeth H. C. Bromley, Adrian P. Brown, David R. W. Hodgson, Tim R. Blower, Jan R. R. Verlet, Matteo T. Degiacomi, Lars-Olof Pålsson, Martin J. Cann
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-10 (2022)
The transfer of electronic energy through a photosystem can harm the photosynthetic apparatus when not balanced with CO2 fixation. Here, the authors show that CO2 modulates electronic energy transfer in cyanobacteria by binding to and enhancing the a
Externí odkaz:
https://doaj.org/article/29c36c67df1547bd98af571796e98e1b
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-6 (2022)
Pyruvic acid and its conjugate base, the pyruvate anion, are largely present in the atmosphere. Here the authors, using photoelectron imaging and quantum chemistry calculations, investigate the photochemistry of isolated pyruvate anions initiated by
Externí odkaz:
https://doaj.org/article/832db82d3a8648878b514f5fdc3d3ea3
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
Resolving concerted nuclear and electronic motion in real-time is a primary goal in chemistry. The authors monitor nuclear and valence electronic dynamics in the excited state single-bond isomerisation of a chromophore of photoactive yellow protein,
Externí odkaz:
https://doaj.org/article/0c084519445345f1af5fca927fca9076
Publikováno v:
Nature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
Photoactive biomolecules rely on chromophores whose photochemistry depends on the environment. Here, the excited state dynamics of a model for the anionic biochromophore in photoactive yellow protein is investigated by time-resolved photoelectron spe
Externí odkaz:
https://doaj.org/article/dbdece9cde0e4b90a4c23f36271f2eb2
Publikováno v:
Journal of the American Chemical Society, 2022, Vol.144(31), pp.14012-14015 [Peer Reviewed Journal]
Molecular photodynamics can be dramatically affected at the water/air interface. Probing such dynamics is challenging, with product formation often probed indirectly through its interaction with interfacial water molecules using time-resolved and pha
Unraveling the decarboxylation dynamics of the fluorescein dianion with fragment action spectroscopy
Autor:
Jemma A. Gibbard, Jan R. R. Verlet
Publikováno v:
The Journal of Chemical Physics. 158
The decarboxylation dynamics of the doubly deprotonated fluorescein dianion, Fl2−, are investigated by recording fragment action spectra for the anion, Fl−, and its decarboxylated analog, Fl–CO2−, using a new reflectron secondary mass spectro
Publikováno v:
Molecules, Vol 26, Iss 10, p 2877 (2021)
A carboxylated adenosine analog (C-Ado−) has been synthesized and probed via time-resolved photoelectron spectroscopy in order to induce intra-molecular charge transfer from the carboxylic acid moiety to the nucleobase. Intra-molecular charge trans
Externí odkaz:
https://doaj.org/article/43f6e2984fcc4520b1880c0c3f90c83a
Autor:
Jan R. R. Verlet, Diana L. Flindt, Aude Lietard, Caleb J. C. Jordan, Jacquie M. Robson, Martin A. Screen
Publikováno v:
Journal of Chemical Education, 2021, Vol.98(12), pp.3871-3877 [Peer Reviewed Journal]
A dual-function student-crafted instrument is described as part of a laboratory activity aimed to teach both the principles and practical aspects of absorption spectroscopy to secondary and introductory undergraduate students. Using minimal changes i