Zobrazeno 1 - 10
of 131
pro vyhledávání: '"R. Rubio Gonzalez"'
Publikováno v:
European Journal of Organic Chemistry. 2018:4926-4932
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bb4e55bb1b90964f4989503c77217548
https://doi.org/10.1002/ejoc.201800800
https://doi.org/10.1002/ejoc.201800800
Publikováno v:
European Journal of Organic Chemistry. 2015:548-555
A radical coupling reaction of diverse vinyl sulfones and epoxides was mediated by Cp2TiCl (Cp = cyclopentadienyl) to provide a straightforward synthetic pathway to hydroxy sulfones. The reaction was successfully achieved by using either an excess or
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3323dae70c7e3173e820d2fc73851933
https://doi.org/10.1002/ejoc.201403288
https://doi.org/10.1002/ejoc.201403288
Publikováno v:
Tetrahedron. 69:1611-1616
The reaction of several stereoisomeric epoxy alcohols, obtained from R-(−)-carvone, and their corresponding formates, acetates, and benzoates, promoted by Cp2TiCl has been studied. The different outcomes of the reaction of epoxy derivatives are rat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a4255e65c217f7e168ced38eff2f8e28
https://doi.org/10.1016/j.tet.2012.11.093
https://doi.org/10.1016/j.tet.2012.11.093
Publikováno v:
Tetrahedron. 67:9529-9534
A practical, brief and selective synthesis of several pinene oxide derived terpenoids can be achieved from readily available starting materials. The key step is a radical reaction promoted by titanocene chloride.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a36af15863bbcde1784569be9f99552d
https://doi.org/10.1016/j.tet.2011.10.004
https://doi.org/10.1016/j.tet.2011.10.004
Autor:
Alfonso Fernández-Mateos, P. Herrero Teijón, G. Pascual Coca, Monique S. J. Simmonds, R. Rubio Gonzalez
Publikováno v:
Tetrahedron. 66:7257-7261
A practical, brief and selective synthesis of limonoid CDE fragments from a readily available starting diketone is described. The key step is a cationic electrocyclization promoted by strong acids. In general the methodology has been demonstrated for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::96699c2d9b4efa6fe343e1f7ee0c350c
https://doi.org/10.1016/j.tet.2010.07.020
https://doi.org/10.1016/j.tet.2010.07.020
Publikováno v:
European Journal of Organic Chemistry. 2010:856-861
The reaction of a series of 2,3-epoxy alcohols and the corresponding formates, acetates, and benzoates promoted by Cp2TiCl has been studied. The different outcome of the reaction of epoxy derivatives has been rationalized in terms of mechanistically
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7f1ce94848ff5ea44bf30e9087a54ad9
https://doi.org/10.1002/ejoc.200901222
https://doi.org/10.1002/ejoc.200901222
Publikováno v:
Synlett. 2008:3208-3212
A new radical clock based on pinene derivatives has been designed to measure the radical cyclization rate onto cyano and carbonyl groups and the radical elimination rate of OR and CN. In this system, the known rate constant of cyclobutylcarbinyl radi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::66e8c779275cd57d3ae9e0f854e1e9f2
https://doi.org/10.1055/s-0028-1087410
https://doi.org/10.1055/s-0028-1087410
Autor:
L. Mateos Buron, Alfonso Fernández-Mateos, P. Herrero Teijón, R. Rubio Gonzalez, R. Rabanedo Clemente
Publikováno v:
The Journal of Organic Chemistry. 72:9973-9982
The reactions of a series of epoxynitriles and epoxyketones induced by titanocene chloride have been studied. The kinetics of the decyanogenation of beta,gamma-epoxynitriles with Ti(III) corresponds to a radical reaction (k25 approximately 106 s-1),
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::38e7837fa215bd22867cedf7ce8602f6
https://doi.org/10.1021/jo701497e
https://doi.org/10.1021/jo701497e
Autor:
F. Sanz González, Alfonso Fernández-Mateos, R. Rubio Gonzalez, P. Herrero Teijón, R. Rabanedo Clemente
Publikováno v:
Synlett. 2007:2718-2722
Radical cascade cyclizations of unsaturated epoxynitriles induced by titanocene chloride proceed in good yields and with excellent diastereoselectivities. From three to seven stereocenters were created by the reaction and a single isomeric product wa
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b96b1827d1dbe6952f380d03da785bbd
https://doi.org/10.1055/s-2007-991057
https://doi.org/10.1055/s-2007-991057
Publikováno v:
ChemInform. 46
A titanocene-mediated intramolecular radical addition of different epoxy vinyl- and allylsulfones has been achieved. Five- and six-membered ring products were obtained in good to excellent yields in the presence of both 2.2 and 0.2 equiv of Cp2TiCl.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e10ba92ff340ef095106122a179b6f59
https://doi.org/10.1002/chin.201537034
https://doi.org/10.1002/chin.201537034