Zobrazeno 1 - 10
of 10
pro vyhledávání: '"R. N. Shafran"'
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2129-2133
The method of competitive reactions has been used to investigate the activity of p- and α-substituted styrenes and 1-substituted cyclopropylethylenes in reactions with dihalocarbenes. The weakening of the influence of the substituents on the activit
Autor:
R. N. Shafran, Oleg M. Nefedov
Publikováno v:
Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 14:515-518
1. A comparative study of the different methods for obtaining dichlorocarbene was made by the method of “competing” addition. 2. The relative rate constants for the dichloromethylenation of cyclohexene and a number of its 1-substituted derivative
Publikováno v:
Petroleum Chemistry U.S.S.R.. 1:517-524
1. 1. It has been established that methylcyclohexane is more readily alkylated with olefins than unsubstituted cyclohexane under thermal conditions. 2. 2. It has been shown that the main product of the reaction is methylethyleyclohexane, a mixture of
Publikováno v:
Petroleum Chemistry U.S.S.R.. 4:243-251
1. 1. It has been found that, in the presence of a skeletal Co-catalyst dienes are hydrogenated at almost the same rate, irrespective of the degreee of subsititution of carbon atoms at the double bonds. The specific activity of the catalyst in these
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 21:849-853
The structure of the products of the condensation of methyl cyclopropyl ketone on basic catalysts was established, and some of their properties were studied.
Publikováno v:
Chemischer Informationsdienst. 16
Publikováno v:
Chemischer Informationsdienst. 4
Publikováno v:
Chemischer Informationsdienst. 3
Publikováno v:
Chemischer Informationsdienst. 4
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:2585-2586
A convenient preparative method was developed for the synthesis of 3,3-disubstituted cyclopropenes in yields up to 90% for 3,3-dimethylcyclopropene, spiro[2.3]hex-1-ene, and 3-methyl-3-phenylcyclopropene from the corresponding monohalocyclopropanes b