Zobrazeno 1 - 10
of 32
pro vyhledávání: '"R. Le Goaller"'
Publikováno v:
ChemInform. 28
Publikováno v:
Synthetic Communications. 16:63-68
Phenols are easily nitrated at room temperature, with good selectivity, by dilute nitric acid or metallic nitrates, in an acidic two-phase system, even without phase transfert catalyst. The results, in these experimental conditions, suggest an electr
Publikováno v:
Tetrahedron Letters. 19:3259-3262
Publikováno v:
Tetrahedron. 36:237-243
Metallation of a series of weak acids (phenols, alcohols, amines, and aryl methanes, pKa 7.2–33.4) by sodium and potassium hydride in presence of 2.2.1 (with NaH) et 2.2.2 (with KH) cryptands in tetrahydrofuran and benzene seems to involve activati
Publikováno v:
Tetrahedron. 35:1437-1440
The generation of the lithium, sodium and potassium enolates of cyclohexanone using LiH, NaH and KH has been investigated. The utilization of macrocyclic ligands (which selectively complex the metal cation) activated the alkaline hydride reagent. How
Publikováno v:
Synthetic Communications. 12:1163-1169
Polyethylene oxides are shown to promote an efficient dihalocarbene formation from bromo — and chloroform and solid potassium hydroxide — Adducts with olefins are obtained in High yields.
Publikováno v:
Tetrahedron. 36:1223-1226
Phenoxides, alkoxides and potassium amidates generated by KH in THF or benzene at room temperature are easily alkylated in the presence of catalytic quantities of [2.2.2]cryptand, without affecting addition-elimination ratios. Thus, Williamson and Ga
Publikováno v:
Tetrahedron Letters. 23:1681-1684
Resume Acyclic polyethylene oxides exhibit useful catalytic effects in various organic reactions, and can be used in lieu of cryptands and crown ethers as nucleophile activators.
Publikováno v:
Chemischer Informationsdienst. 16
Publikováno v:
Chemischer Informationsdienst. 12