Zobrazeno 1 - 10
of 124
pro vyhledávání: '"R. KLENZE"'
Publikováno v:
ract. 101:561-570
Summary Sorption plays a major role in the safety assessment of nuclear waste disposal. In the present theoretical study we focused on understanding the interaction of trivalent lanthanides and actinides (La3+, Eu3+ and Cm3+) with the corundum (110)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e7ad4f417c874c698f0544f872ebfff9
https://doi.org/10.1524/ract.2013.2054
https://doi.org/10.1524/ract.2013.2054
Autor:
Horst Geckeis, Thomas Fanghänel, Jörg Rothe, Thomas Rabung, Xu-cong Wang, R. Klenze, Melissa A. Denecke
Publikováno v:
Radiochimica Acta. 94:609-618
Sorption of trivalent Cm onto γ-Al2O3is investigated by time-resolved laser fluorescence spectroscopy (TRLFS). The pH dependent sorption of Cm(III) is followed at constant ionic strength of 0.1 M NaClO4under argon atmosphere in the pH range between
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8497b4c86d1604bd84f44c8bfaccdb4f
https://doi.org/10.1524/ract.2006.94.9-11.609
https://doi.org/10.1524/ract.2006.94.9-11.609
Publikováno v:
Radiochimica Acta. 93:133-139
SummaryThe complexation of248Cm(III) with aqueous silicic acid is investigated in the pH range of 1.5–9.0 in 0.03 M NaCl with varying the silicate concentration under and over saturation in reference to the solubility of amorphous silica in order t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::25abd16a8e8cc8a1a561c3facdf83d46
https://doi.org/10.1524/ract.93.3.133.61616
https://doi.org/10.1524/ract.93.3.133.61616
Publikováno v:
Radiochimica Acta. 92:691-695
SummarySorption of Cm(III) ontoγ-alumina coated with humic acid (HA) is studied by the Time Resolved Laser Fluorescence Spectroscopy (TRLFS). The experiments are performed at 0.1 M NaClO4, 0.44 g/Lγ-Al2O3, 10 mg/L HA and at a metal ion concentratio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::47be3e706a309830d07f41481d1d65c7
https://doi.org/10.1524/ract.92.9.691.54982
https://doi.org/10.1524/ract.92.9.691.54982
Publikováno v:
The Journal of Physical Chemistry B. 108:17160-17165
In the present study, Cm(III) sorption onto different crystal planes (018), (104), (012), (110), and (001) of sapphire single crystals (area 1 cm2) is investigated at low Cm(III) concentrations and at pH 4.5 and 5.1 by time-resolved laser fluorescenc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3ddac4b0aeb6d98ef6d6b5d7fbcae2c0
https://doi.org/10.1021/jp040342h
https://doi.org/10.1021/jp040342h
Publikováno v:
Colloids and Surfaces A: Physicochemical and Engineering Aspects. 216:97-108
A study is presented to elucidate how the trivalent actinide ions become incorporated into the formation of aluminosilicate colloids. The acidic Al solution of varying concentration from 10 −5 to 10 −3 mol l −1 , containing the Am 3+ or Cm 3+ i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fa859715253a2508efbd35c667ec0ee3
https://doi.org/10.1016/s0927-7757(02)00501-0
https://doi.org/10.1016/s0927-7757(02)00501-0
Publikováno v:
Applied Spectroscopy. 56:852-858
The paper presents the application of laser-induced breakdown spectroscopy (LIBS) for the on-line multielement analyses of glass melts in a vitrification process of high level liquid waste (HLLW). The third harmonic pulse of an Nd:YAG laser is used f
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d4d7df2c894dbd274942bd8ad6cf853a
https://doi.org/10.1366/000370202760171518
https://doi.org/10.1366/000370202760171518
Publikováno v:
Applied Spectroscopy. 56:437-448
Laser-induced breakdown spectroscopy (LIBS) is presented for the on-line multielement analysis of molten radioactive glass at a simulated vitrification process of high level liquid waste (HLLW). A plasma plume is produced by focusing the third harmon
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fe37849ae5b9caa71c3164897dcf94f1
https://doi.org/10.1366/0003702021955097
https://doi.org/10.1366/0003702021955097
Publikováno v:
Radiochimica Acta. 88:7-17
The complexation of humic acid with Cm(III) and Am(III) is studied in the neutral pH range from 6 to 10 in 0.1 M NaClO4under Ar-atmosphere. Cm(III) and Am(III) species are characterized and quantified by time-resolved laser fluorescence spectroscopy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::45fb249f206b2bbd8ba1321ddb77be96
https://doi.org/10.1524/ract.2000.88.1.007
https://doi.org/10.1524/ract.2000.88.1.007
Publikováno v:
Surface and Interface Analysis. 30:297-300
The importance of humic colloids influencing mobilization or immobilization of metal ions, i.e. actinides, in natural aquatic systems has been emphasized in the context of safety aspects of nuclear waste repositories. The influence of polyvalent cati
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::61fb684b9344b16d55ac6850a0c7e80e
https://doi.org/10.1002/1096-9918(200008)30:1<297::aid-sia789>3.0.co
https://doi.org/10.1002/1096-9918(200008)30:1<297::aid-sia789>3.0.co