Zobrazeno 1 - 10
of 97
pro vyhledávání: '"R. J. Van Zee"'
Publikováno v:
The Journal of Physical Chemistry A. 103:1025-1028
Electron-spin-resonance (ESR) spectroscopy has been applied to vanadium, niobium (and tantalum) complexes with N2 and CO in the corresponding pure solid matrixes at 4 K. Except for V(CO)6, none has previously been studied by ESR. For these d,5 S = 1/
Autor:
William Weltner, R. J. Van Zee
Publikováno v:
Chemical Physics Letters. 300:243-246
The electron-spin-resonance (ESR) spectra of the P3− radical (D3h symmetry) in its X 3 A 2 ′ ground state have been observed in solid neon and argon matrices at 4 K. It is produced during laser-vaporization of solid GaP and is presumably the resu
Publikováno v:
The Journal of Chemical Physics. 107:4756-4759
BH4, with isotopic substitution, has been prepared and trapped in solid H2, D2, HD by laser vaporization of boron and subsequent reaction with the matrix gas. The results confirm the C2v structure of the molecule and generally support the results of
Publikováno v:
The Journal of Physical Chemistry A. 101:2917-2920
Autor:
William Weltner, R. J. Van Zee
Publikováno v:
Chemical Physics Letters. 266:403-409
The ions, Ni + , Pd + , Pt + (all having 2 D 5 2 ground electronic states) were produced in the plasma formed during laser vaporization of the metals and directly trapped in solid argon and krypton at 4 K. Electron-spin-resonance (ESR) spectra indica
Publikováno v:
The Journal of Chemical Physics. 106:2583-2588
Laser-vaporized platinum metal, trapped in solid Ne, Ar, Kr, Xe (and Ar, Kr mixture) produced a progression of absorption bands with a spacing of ∼200 cm−1 beginning at 1942 cm−1 in Ne and shifting successively to 1579 cm−1 in Xe. In contrast
Publikováno v:
The Journal of Chemical Physics. 106:2055-2059
Two vibronic transitions, 2Δ3/2(v=0)←2Δ5/2(v″=0) and 2Π3/2(v=0)←2Δ5/2(v″=0) at 923 and 2560 cm−1, respectively, were observed for NiH in solid argon (and krypton) at 4 K. These Ω=3/2←Ω=5/2 transitions were shifted and broadened by m
Publikováno v:
Chemical Physics Letters. 262:298-302
Ground-state vibrational frequencies of the matrix-isolated B3 and Al3 molecules have been observed. For Al3 there also appears a progression of bands beginning at ≈ 1800 cm−1, which is attributed to absorption to a low-lying electronic state.
Publikováno v:
The Journal of Chemical Physics. 103:2762-2765
Electron‐spin‐resonance (ESR) spectroscopy of these molecules in argon matrices at 2 K reveals that each has a 4∑ ground electronic state, the same as TiV, also containing 9 valence (s+d) electrons. TiTa and ZrTa were not observed. An analogy c
Publikováno v:
The Journal of Physical Chemistry. 99:6277-6285
$^{a}$W. Weltner, Jr., R.J. Van Zee, and S. Li. J. Phys. Chem. 99, 6277 (1995). $^{b}$Y.M. Hamrick and W. Weltner, Jr.,. J. Chem. Phys. 94 3371 (1991). $^{c}$R.J. Van Zee and W. Weltner, Jr., Chem. Phys. Lett (accepted). $^{d}$S. Li, H.A. Weimer, R.J