Zobrazeno 1 - 10
of 415
pro vyhledávání: '"R. G. Kostyanovskii"'
Publikováno v:
Russian Journal of Physical Chemistry A. 88:667-670
The molecular structure of (cyanomethoxy)(dimethylamino)methane in the gas phase is investigated by means of gas-phase electron diffraction and quantum-chemical studies for the first time. It is shown that in the gaseous state, (cyanomethoxy)(dimethy
Autor:
Sergey V. Stovbun, A. M. Zanin, Ya. A. Litvin, A. A. Skoblin, R. G. Kostyanovskii, D. S. Skorobogat’ko, A. I. Mikhailov, O. N. Krutius
Publikováno v:
Russian Journal of Physical Chemistry B. 6:341-347
The chirooptical properties of a number of compounds in a variety of achiral solvents are studied. The results are interpreted within the framework of the standard model of chiral molecules. It is demonstrated that, with increasing concentration, chi
Autor:
A. A. Skoblin, A. I. Mikhailov, R. G. Kostyanovskii, B. R. Shub, Sergey V. Stovbun, M. V. Grishin, A. M. Zanin
Publikováno v:
Russian Journal of Physical Chemistry B. 5:1019-1022
The macroscopic chirality of strings in xerogel obtained from a solution of N-trifluoroacetyl-R(+)-valinol in cyclohexane was revealed by atomic force microscopy and circular dichroism. The characteristic plots on different scales are reported, namel
Publikováno v:
Russian Journal of Physical Chemistry B. 5:846-849
Gelators with a molecular mass of 200 Da are synthesized, and the mechanisms of the formation of anisotropic supramolecular structures during the gelation of N-trifluoroacetyl derivatives of amino alcohols are discussed. The conditions of their stabi
Publikováno v:
Russian Chemical Bulletin. 64:960-961
A new bicyclic aziridino lactone 1 was synthesized from methyl 2,3-dibromopropionate and 2-amino-2-methylpropane-1,3-diol (AMPD). The reaction of compound 1 with benzyl chloroformate and subsequent treatment of the intermediate compound with 1,8-diaz
Autor:
A. P. Pleshkova, V. F. Rudchenko, V. M. Grinev, Vasiliy G. Shtamburg, R. G. Kostyanovskii, A. A. Dmitrenko
Publikováno v:
ChemInform. 23
The addition of N-chloro-N-methoxy-tert-alkylamines to an olefin, which is assumed to proceed with the participation of alkoxynitrenium ions, was carried out for the first time. The methanolysis of N-chloro-N-alkoxy-tert-alkylamines in the presence o
Autor:
A. B. Zolotoi, S. V. Konovalikhin, L. O. Atovmyan, Yu. I. El'natanov, R. G. Kostyanovskii, I. I. Chervin
Publikováno v:
ChemInform. 28
Publikováno v:
ChemInform. 28
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 22
1-Alkoxyaziridine-2~2-dicarboxylic acid esters III are of interest in connection with the high pyramidal stability of the nitrogen atom [1]. The principal method for their synthesis is the reaction of alkoxyiminomalonates with diazomethane at 20~ [2]