Zobrazeno 1 - 10
of 75
pro vyhledávání: '"R. F. Rekker"'
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 70:113-126
The reaction between an isocyanate and an α-hydroxy-ester leads to the formation of an N-substituted carbamylo-α-hydroxy-ester, which can give an oxazolidinedione-2,4 under the influence of a small amount of metallic sodium by ring closure with the
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 80:792-796
From a quantity of ethyl mandelate there separated, after prolonged storage, a crystalline compound, which was found to consist of mandelic acid and ethyl mandelate in a 1 : 1 ratio. This product can also be prepared in situ by mixing equivalent amou
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 73:410-416
To aconic acid, first described in literature by Kekule, the structure of a β,γ-butenolide was given by Fittig and Beer. In 1947 Campbell and Hunt put forward arguments for an α,β-butenolide structure. These arguments were based on a new synthesi
Autor:
W. Th. Nauta, R. F. Rekker
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 79:843-853
Controversial structures have been assigned 1,2 to the nitrogen-containing carboxylic acid which is one of the products formed on hydrolysis of N-substituted oxazolidinediones-2,4. The present publication solves the problem in favour of our previous
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 84:1348-1356
Several 2-alkyl-1-(ortho-alkyl)phenylcyclohexanols have been synthesized from lithium compounds (obtained from alkylbromobenzenes) and 2-alkyl-cyclohexanones. G.L.C. analysis has shown that only one isomer is formed. The conformation was elucidated w
Autor:
R. F. Rekker, W. Th. Nauta
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 80:747-763
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 70:675-680
The U.V. absorption spectra of p.amino-salicylic acid were measured both in water and in ethanol. The results of these measurements show that there is no discrepancy between the work of Way a.o. and Drain a.o. as was suggested by the latter authors.
Autor:
W. Th. Nauta, R. F. Rekker
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 90:343-351
The UV absorption spectra of a small series of aromatic tricyclic ketones derived from benzophenone by introduction of an interconnecting -(CH2)n-bridge (n = 1, 2, or 3) are described. The spectra show well-defined steric effects in the 270-nm region
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 86:609-621
Composite hydrolytic dissociation constants, KI and KII, of 4-aminobenzoic acids substituted as follows, 2-H-, 2-CH3-, 2-Cl-, 2-Br-, 2-NO2-, 2-OH-, 2-OCH3-, 3-Br-, 2,6-(CH3)2-, 2,6-(C2H5)2-, 2,6-Cl2- and 2,6-Br2-, have been determined in aqueous solu
Autor:
R. F. Rekker, W. Th. Nauta
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 80:764-774
This article gives the experimental results of UV measurements made on a number of benzophenones with ethyl, isopropyl and tert.butyl groups as substituents. The results are compared with the previously published data on the corresponding methyl-subs