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pro vyhledávání: '"R. Dale Rimmer"'
Publikováno v:
Coordination Chemistry Reviews. 256:1509-1519
The potential therapeutic effects of carbon monoxide in several disease states, and new methodologies for CO delivery to specific targets is a topic of growing interest in mammalian physiology. Here we provide an overview of recent efforts in this la
Publikováno v:
Inorganic Chemistry. 48:231-238
Photolysis of the thionitrosyl complex Cr(CH3CN)5(NS)2+ (1) in acetonitrile solution leads to the dissociation of nitrogen monosulfide (NS). In deaerated solution, this reaction is reversible, and flash photolysis studies demonstrate that NS reacts w
Autor:
James F. Wishart, Ilya A. Shkrob, Jasmine L. Hatcher, Sheng Dai, Huimin Luo, R. Dale Rimmer, Timothy W. Marin, Jason R. Bell
Publikováno v:
The journal of physical chemistry. B. 116(7)
N,N,N',N'-Tetraalkyldiglycolamides are extracting agents that are used for liquid-liquid extraction of trivalent metal ions in wet processing of spent nuclear fuel. This application places such agents in contact with the decaying radionuclides, causi
Publikováno v:
Inorganic chemistry. 49(3)
Interest in therapeutic applications of carbon monoxide release to physiological targets has led us to explore a photochemical strategy for such CO delivery. Here, we describe the photoactivated carbon monoxide releasing moiety (photoCORM), W(CO)(5)(
Publikováno v:
Journal of the American Chemical Society. 129:15430-15431
Spin triplet (PNP)Co adds one CO according to a rate law first-order in each reagent with k = 9.3 × 105 M-1 s-1. In contrast, the transient produced by photodissociation of CO from (PNP)Rh(CO) forms, within 10 ns, the Rh(III) species [η4-tBu2PCH2Si
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