Zobrazeno 1 - 10
of 109
pro vyhledávání: '"R. Bougon"'
Autor:
L. Arnaudet, B. Buu, Martine Nierlich, Julien Vigner, R. Bougon, Pierre Thuéry, Monique Lance
Publikováno v:
Journal of Fluorine Chemistry. 71:123-129
Adducts of tungsten(VI), i.e. WF 6 ·py and WF 6 ·2py (py = pyridine) have been characterized by X-ray diffraction data and vibrational spectroscopy. Solutions of these adducts in CD 2 Cl 2 have also been studied by 19 F, 1 H and 13 C NMR spectrosco
Publikováno v:
Journal of Fluorine Chemistry. 67:271-276
The fluorination of ruthenium dioxide, RuO 2 , and osmium di- and tetra-oxides, OsO 2 and OSO 4 , has been studied at ambient temperature using fluorinating agents of variable strength such as chlorine trifluoride ClF 3 , bromine pentafluoride BrF 5
Publikováno v:
Journal of Fluorine Chemistry. 67:17-25
The complex [WF 4 (bipy) 2 ] 2+ ·2[WF 7 ] − ·WF 6 has been obtained by the reaction of excess WF 6 with 2,2'-bipyridyl (bipy) in acetonitrile solution, and the complex [WF 4 (bipy) 2 ] 2+ ·2[WF 7 ] − CH 3 N resulted from treatment of [WF 4 (bi
Publikováno v:
Chemische Berichte. 126:1331-1336
The new method for preparing OsO3F2 is presented. Its crystal structure reveals a polymeric chain structure with distorted octahedral geometry for the OsO3F3 units and symmetrical, non-linear fluorine bridges. The OsO3F3 unit has a facial geometry. T
Publikováno v:
ChemInform. 22
Autor:
R. Bougon
Publikováno v:
ChemInform. 23
Osmium oxide hexafluoride OsOF 6 is prepared by fluorination of osmium tetraoxide using krypton difluoride in HF solution. This new Os (VIII) derivative is characterized by elemental analysis, X-ray powder data and vibrational spectroscopy. The fluor
Publikováno v:
ChemInform. 24
The new method for preparing OsO3F2 is presented. Its crystal structure reveals a polymeric chain structure with distorted octahedral geometry for the OsO3F3 units and symmetrical, non-linear fluorine bridges. The OsO3F3 unit has a facial geometry. T
Publikováno v:
Journal of Fluorine Chemistry. 59:141-152
The complex [WF 4 (bipy) 2 ] 2+ · 2[W 2 O 2 F 9 ] − · 0.25HF has been obtained by the controlled hydrolysis of a mixture of WF 6 and 2,2′-bipyridyl (bipy) in CD 2 Cl 2 solution. The crystal structure of this complex has been determined from X-r
Autor:
R. Bougon
Publikováno v:
Journal of Fluorine Chemistry. 53:419-427
Osmium oxide hexafluoride OsOF 6 is prepared by fluorination of osmium tetraoxide using krypton difluoride in HF solution. This new Os (VIII) derivative is characterized by elemental analysis, X-ray powder data and vibrational spectroscopy. The fluor
Publikováno v:
Journal of Fluorine Chemistry. 53:171-180
The adducts WOF4.napy and WOF4.dmnapy were prepared from the reaction of WOF4 with 1,8-naphthyridine (napy) and 2,7-dimethyl-1,8-naphthyridine (dmnapy) in dichloromethane. Both adducts were characterized by elemental analysis, X-Ray powder data and i