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Spontaneous generation of stable pnictinyl radicals from 'jack-in-the-box' dipnictines: a solid-state, gas-phase, and theoretical investigation of the origins of steric stabilization

Autor: S L, Hinchley, C A, Morrison, D W, Rankin, C L, Macdonald, R J, Wiacek, A, Voigt, A H, Cowley, M F, Lappert, G, Gundersen, J A, Clyburne, P P, Power

Publikováno v: Journal of the American Chemical Society. 123(37)

The molecular structures of the stable phosphinyl and arsinyl radicals, .PnR(2) [Pn = P (2); As (4); R = CH(SiMe(3))(2)], have been determined by gas-phase electron diffraction (GED) in conjunction with ab initio molecular orbital calculations. The X

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::71d0f4ad046998133c1ade4084fd15be
https://pubmed.ncbi.nlm.nih.gov/11552812

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Akademický článek

Supercritical Fluid–Liquid–Solid Synthesis of Gallium Arsenide Nanowires Seeded by Alkanethiol-Stabilized Gold NanocrystalsThis work was supported by the NSF, the Welch Foundation and the Texas Higher Education Coordinating Board through their ATP program. We thank Tobias Hanrath and Cindy Stowell for valuable discussions. Supporting information is available online from Wiley Interscience or from the authors.

Autor: F. M. Davidson, A. D. Schricker, R. J. Wiacek

Publikováno v: Advanced Materials; Apr2004, Vol. 16 Issue 7, p646-649, 4p

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