Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Rüdiger Stieglitz"'
Publikováno v:
ARKIVOC, Vol 2012, Iss 3, Pp 442-456 (2012)
Externí odkaz:
https://doaj.org/article/b502ef1ff0e34b308b9cc31512b53965
Publikováno v:
Zeitschrift für Naturforschung B. 74:913-924
From acetone and the orthoamide of phenylpropiolic acid (21b) N,N-dimethyl-phenylpropiolic acid amide (24) is formed. In contrast, the reaction of chloroacetone (28) with 21b results in the vinylogous guanidinium chloride 29. Unexpectedly, the Bircke
Publikováno v:
Zeitschrift für Naturforschung B. 74:925-938
The 1,1-bis(dimethylamino)-1,3-butadienes (keten aminals) 11a–l are prepared from orthoamide derivatives of alkyne carbonxylic acids 9b, d, e, i and CH2-acidic compounds 10a–c, f–h, k, o. The C-silylated orthoamide derivative 9c shows an ambiva
Publikováno v:
Synthesis. 44:3090-3094
Orthoamides of six alkynecarboxylic acids, possessing reactive substituents in 3-position, are transformed by elemental iodine to the corresponding vinylogous guanidinium iodides. The constitution of two of the iodides was established by crystal-stru
Publikováno v:
ARKIVOC, Vol 2012, Iss 3, Pp 442-456 (2012)
Autor:
Jochen Mezger, Kai Edelmann, Rüdiger Stieglitz, Hansjörg Lehmann, Sebastian Ladendorf, Willi Kantlehner, Markus Vettel, Ralf Kreß, Wolfgang Frey
Publikováno v:
Zeitschrift für Naturforschung B. 62:1015-1029
The orthoamide derivatives 4 react with amidines 10 and guanidines 11 to give 4-dimethylaminopyrimidines 12. The 3-dimethylamino-pyrazoles 13a - c can be prepared from orthoamides 4 and hydrazine. The hydrazine derivative 14, whose constitution was e
Publikováno v:
Zeitschrift für Naturforschung B. 57:399-419
The orthoamide derivatives 1s and 2e were prepared from the guanidinium salt 7a and the appropriate carbanions. Cleavage of the orthoamide 2e with benzoyl chloride affords the amidinium salt 10a, which can be transformed into the amidinium salt 10b b
Publikováno v:
Journal für praktische Chemie. 342:256-268
The formamidinium salts 11a, c as well as the nitrile 12 react with sodiumhydride/dimethylamine in the presence of trimethylborate to give the ortho formic acid amide 3a. The orthoamides 6a and 16 can be prepared from the iminium salts 15 and 14, res
Autor:
Kai Edelmann, Ivo C. Ivanov, Markus Vettel, Hansjörg Lehmann, Rüdiger Stieglitz, Willi Kantlehner
Publikováno v:
Journal f�r Praktische Chemie/Chemiker-Zeitung. 340:408-423
Orthoamides. LI. Push-Pull-Butadienes and Heterocycles from Alkyne Carboxylic Acid Orthoamides and CH2-acidic Compounds The acetylides 4b, 4f react with N,N,N′,N′,N″,N″-hexamethylguanidiniumchloride (5) to give the orthoamides 6b, 6f, resp. F
Publikováno v:
Synthesis; 2012, Vol. 44 Issue 19, p3090-3094, 5p