Zobrazeno 1 - 10
of 134
pro vyhledávání: '"Rüdiger, Bertermann"'
Autor:
Lin Wu, Marco Holzapfel, Alexander Schmiedel, Fuwei Peng, Michael Moos, Paul Mentzel, Junqing Shi, Thomas Neubert, Rüdiger Bertermann, Maik Finze, Mark A. Fox, Christoph Lambert, Lei Ji
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-10 (2024)
Abstract Icosahedral carboranes, C2B10H12, have long been considered to be aromatic but the extent of conjugation between these clusters and their substituents is still being debated. m- and p-Carboranes are compared with m- and p-phenylenes as conju
Externí odkaz:
https://doaj.org/article/b3c4e902b9654d279d5f67315150e93d
Autor:
Younes K. J. Bejaoui, Frederik Philippi, Hans-Georg Stammler, Krzysztof Radacki, Ludwig Zapf, Nils Schopper, Kateryna Goloviznina, Kristina A. M. Maibom, Roland Graf, Jan A. P. Sprenger, Rüdiger Bertermann, Holger Braunschweig, Tom Welton, Nikolai V. Ignat'ev, Maik Finze
Publikováno v:
Chemical Science. 14:2200-2214
Room temperature ionic liquids of cyclic sulfonimide anions ncPFSI (ring size: n = 4-6) with the cations [EMIm]+ (1-ethyl-3-methylimidazolium), [BMIm]+ (1-butyl-3-methylimidazolium) and [BMPL]+ (BMPL = 1-butyl-1-methylpyrrolidinium) have been synthes
Autor:
Annalena Gärtner, Lukas Meier, Merle Arrowsmith, Maximilian Dietz, Ivo Krummenacher, Rüdiger Bertermann, Felipe Fantuzzi, Holger Braunschweig
Publikováno v:
Journal of the American Chemical Society. 144:21363-21370
The stepwise reduction of a doubly cyclic alkyl(amino)carbene (CAAC)-stabilized 2,3-bis(dibromoboryl)naphthalene enables the isolation of the corresponding mono- and bis(boryl) radicals (one- and two-electron reduction), a 2π-aromatic 1,2-diborete (
Publikováno v:
Dalton Transactions. 51:13488-13498
The synthesis and characterization of NHC and cAACMe ligated Pb(ii) and Pb(iv) compounds are presented.
Autor:
Lisa C. Haufe, Merle Arrowsmith, Maximilian Dietz, Annalena Gärtner, Rüdiger Bertermann, Holger Braunschweig
Publikováno v:
Dalton Transactions. 51:12786-12790
The spontaneous 1,3-bromoboration of a tungsten dinitrogen complex with B2Br2(SMe2)2 yields diazenidodiborane complexes.
Autor:
Vargini G. Thangavadivale, Lukas Tendera, Rüdiger Bertermann, Udo Radius, Torsten Beweries, Robin N. Perutz
Publikováno v:
Faraday Discussions.
Halogen and hydrogen bonding using bis(carbene) nickel fluoride complexes as acceptors and suitable halogen and hydrogen bond donors is presented, showing interactions that are much stronger than those of related phosphine supported nickel fluorides.
Autor:
Eleonora Cataldi, Martina Raschig, Marcus Gutmann, Patrick T. Geppert, Matthias Ruopp, Marvin Schock, Hubert Gerwe, Rüdiger Bertermann, Lorenz Meinel, Maik Finze, Agnieszka Nowak‐Król, Michael Decker, Tessa Lühmann
Publikováno v:
Chembiochem : a European journal of chemical biology.
The incorporation of photoswitches into the molecular structure of peptides and proteins enables their dynamic photocontrol in complex biological systems. Here, a perfluorinated azobenzene derivative triggered by amber light was site‐specifically c
Autor:
Johannes Landmann, Tanja Knuplez, Christoph Kerpen, Nikolai V. Ignat'ev, Ludwig Zapf, Rüdiger Bertermann, Kristina A. M. Maibom, Tobias Bischof, Fabian Keppner, Eva-Maria Tanzer Krauel, Carl Deutsch, Leon Schneider, Klaus Urbahns, Michael Hailmann, Maik Finze
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Fluorinated groups are essential for drug design, agrochemicals, and materials science. The bis(trifluoromethyl)amino group is an example of a stable group that has a high potential. While the number of molecules containing perfluoroalkyl, perfluoroa
Publikováno v:
European Journal of Inorganic Chemistry. 2022
A study on the reactivity of N‐heterocyclic carbenes (NHCs) and the cyclic (alkyl)(amino)carbene cAAC\(^{Me}\) with selected germanium(IV) and tin(IV) chlorides and organyl chlorides is presented. The reactions of the NHCs Me\(_{2}\)Im\(^{Me}\), iP
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany).
A study of the reactivity of several N‐heterocyclic carbenes (NHCs) and the cyclic (alkyl)(amino)carbene 1‐(2,6‐di‐iso‐propylphenyl)‐3,3,5,5‐tetramethyl‐pyrrolidin‐2‐ylidene (cAAC\(^{Me}\)) with the group 14 hydrides GeH2Mes2 and