Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Qingheng, Lai"'
Autor:
Qingheng Lai, Alexander H. Mason, Amol Agarwal, Wilson C. Edenfield, Xinrui Zhang, Takeshi Kobayashi, Yosi Kratish, Tobin J. Marks
The novel electrophilic organo-tantalum catalyst AlS/TaNp () (Np = neopentyl) is prepared by chemisorption of the alkylidene Ta(CHtBu)Np onto highly Brønsted acidic sulfated alumina (AlS). The proposed catalyst structure is supported by EXAFS, XANES
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a94fd7ed4223ae777dcd1d014c3478d2
https://doi.org/10.26434/chemrxiv-2023-24gfx
https://doi.org/10.26434/chemrxiv-2023-24gfx
Autor:
Qingheng Lai, Oleg V. Ozerov, Rafael Huacuja, Jerzy Klosin, Sean Bremer, Senecal Todd D, Pearson David M, Jessica C. DeMott, Nattamai Bhuvanesh, S. Olivia Gunther
Publikováno v:
ACS Catalysis. 11:3335-3342
Several ammonium carborane salts ([HNR3][HCB11X11], X = H, Me, Cl) were prepared and evaluated as activators with bis-metallocene and constrained geometry precatalysts at 140 and 190 °C. Activators...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5e4af473c1659d0e38a813691b465f80
https://doi.org/10.1021/acscatal.0c04228
https://doi.org/10.1021/acscatal.0c04228
Publikováno v:
Journal of the American Chemical Society. 142:20920-20923
We report the synthesis of PAlP and PBP pincer complexes of Rh with a central bis(N-pyrrolyl)aluminyl or -boryl unit. Complex (PAlpyP)Rh(CO)2 possesses an aluminyl site stabilized by coordination of pyridine, resulting in a four-coordinate Al. Attemp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1530e543bca0d9e9195815e427c5792e
https://doi.org/10.1021/jacs.0c09344
https://doi.org/10.1021/jacs.0c09344
Autor:
Qingheng Lai, Chen-Hao Wang, Nattamai Bhuvanesh, Oleg V. Ozerov, Xin Yang, Cheng-Han Yu, Xiaozhou Ji
Publikováno v:
Inorganic Chemistry. 59:10153-10162
A series of binuclear homo- and heterobimetallic complexes of the general type (PNP)M-[linker]-M(PNP) have been prepared (M = Ni, Pd, Pt; PNP = a diarylamido/bis(phosphine) pincer ligand; -[linker]- = -C≡C-, -C≡CC≡C-, -C≡CC
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::12829fe8ec9f25c06f5313ad569a89a3
https://doi.org/10.1021/acs.inorgchem.0c01281
https://doi.org/10.1021/acs.inorgchem.0c01281
Publikováno v:
Chemical Communications. 56:14845-14848
Syntheses of a new tripodal alane/tris(phosphine) ligand (AlP3) based on 2-(diisopropylphosphino)pyrrole, and AlP3-supported Ni complexes are reported. The central tris(pyrrolyl)aluminum moiety acts as a stronger Lewis acid towards Ni than other rela
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::15a5b8bbc410de0aa6d9df9aba592c94
https://doi.org/10.1039/d0cc05452f
https://doi.org/10.1039/d0cc05452f
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 50(17)
An alane/tris(phospine) ligand reacts with AgOTf by coordination of three phosphines to the Ag center and transfer of triflate to the tris(pyrrolyl) Al site. Reaction with Ag[HCB11Cl11] results in the coordination of two phosphines to Ag and one to A
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3d04ea9f318729ee47638d22975ba452
https://pubmed.ncbi.nlm.nih.gov/33881441
https://pubmed.ncbi.nlm.nih.gov/33881441
Publikováno v:
Chemical communications (Cambridge, England). 56(94)
Syntheses of a new tripodal alane/tris(phosphine) ligand (AlP3) based on 2-(diisopropylphosphino)pyrrole, and AlP3-supported Ni complexes are reported. The central tris(pyrrolyl)aluminum moiety acts as a stronger Lewis acid towards Ni than other rela
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::5434e3ab99c11c05d56eb8cb7b9d0373
https://pubmed.ncbi.nlm.nih.gov/33174873
https://pubmed.ncbi.nlm.nih.gov/33174873
Autor:
Oleg V. Ozerov, Qingheng Lai
Publikováno v:
Journal of Organometallic Chemistry. 931:121614
Catalytic dehydrogenative diboration (DHDB) of alkyne with HBpin was achieved using [Ir(COD)Cl]2 and other related Ir precursors under CO atmosphere. The selectivity for DHDB over hydroboration was higher in less polar solvents and under higher CO pr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f96c0c650a20994aee60915c2052f973
https://doi.org/10.1016/j.jorganchem.2020.121614
https://doi.org/10.1016/j.jorganchem.2020.121614