Zobrazeno 1 - 10
of 41
pro vyhledávání: '"Qiang-Jin Wu"'
Publikováno v:
Chinese Journal of Chemistry. 15:417-424
A dinuclear molybdenum(V) cluster compound (Et4N)2[Mo2S4(i-mnt)2] (i-mnt=1,1-dicyanoethylene-2,2-dithiol, [S2C=C(CN)2]2-) has been prepared by the ligand substitution reaction of Mo2S4(iso-pr2dtp)2 (iso-pr2dtp=S2P(OC3H7)2−) with K2(i-mnt) in the pr
Publikováno v:
Chinese Journal of Chemistry. 15:296-303
A new cluster compound {[Mo3(μ3-O)(μ-S)3(dtp)3(py)3][CdI(dtp)2]} (dtp=S2P(O-C2H5)−2) was obtained from the reaction of [Mo3OS3(dtp)4(H2O)] with a CdI2-Bu4NI mixture. The molecular structure is composed of a cluster cation [Mo3OS3(dtp)3(py)3]+ and
Publikováno v:
Journal of Chemical Crystallography. 33:165-168
The crystal structure of syn-1-acetyl-9′a-hydro-8′-methoxyspiro[3H-indole-3,2′(2a′H) oxeto[3,2-g]furo[3,2-g]benzo[ b]pyran-2,6′-dione 1 was determined by X-ray diffraction analysis. It possesses P2(1)/c space group symmetry, with a = 12.391
Publikováno v:
Journal of Chemical Crystallography. 33:795-798
1-Methyl-2-phenylindolizine-3-acetonitrile was unexpectedly obtained in the reaction of 1-methyl-2-phenylindolizine-3-thioaldehyde with cyanide ions. Its structure was determined by IR, 1H NMR, MS, elemental analyses, and X-ray crystallography. Color
Autor:
Zi-Xiang Huang, Chun-Mei Zhang, Jie Zhang, Zu-En Huang, Ming Zhu, Lixin Zhang, Ruifang Cai, Xigeng Zhou, Qiang-Jin Wu
Publikováno v:
Journal of Organometallic Chemistry. 655:120-126
Reactions of anhydrous lanthanide trichloride with one or two equivalent of tert -butyldimethylsilylcyclopentadienyl (Cp t ) potassium salt in THF afford mono( tert -butyldimethylsilylcyclopentadienyl)lanthanide dichloride complexes Cp t LnCl 2 (THF)
Publikováno v:
Journal of Cluster Science. 13:15-31
Three new heterometallic tetranuclear cluster compounds with a [Mo3YS3M′] cubane-like cluster core (M′=Cu, Pb, Sb; Y=O, S), [Mo3OS3(CuI)(μ-OAc)2(dtp)2(DMF)] (1), (dtp=S2P(OC2H5)−2), [Mo3OS3(PbI3)(dtc)3(py)3] (2) (dtc=S2CN(C2H5)−2), [Mo3S4(Sb
Publikováno v:
Organometallics. 20:5700-5706
Cp‘2LnR(THF) (Cp‘ = C5H4CH3) reacted with phenyl isocyanate to form the PhNCO insertion products [Cp‘2Ln(OC(R)NPh)]2 [R = n-butyl, Ln = Sm (1), Dy (2), Er (3); R = α-naphthyl, Ln = Dy (4)]. It was found that an excess of PhNCO did not affect t
Autor:
Daxu Wu, Ying Peng, Jin Chen, Yu Zheng, Shao-Fang Lu, Xiao-Ying Huang, Jian-Quan Huang, Rongmin Yu, Zi-Xiang Huang, Qiang-Jin Wu
Publikováno v:
Polyhedron. 20:2339-2352
For the heterometallic cluster compounds containing a core of [M3YS3M] (4 + n)+ (M= Mo, W; Y= O, S; M= metal atom except Mo, W), a relatively comprehensive understanding has already been made when M n + appears to be a transition metal. When M n + is
Publikováno v:
Organometallics. 20:3293-3298
Publikováno v:
Chemistry. 7:2002-2006
Reaction of [Mo3Y(μ-S)3(dtp)4(H2O)] (Y=O, S; dtp=S2P(OC2H5)2−) with HgI2 gave the novel compound {[Mo3S7(dtp)3]4⋅I}{(HgI3)3}⋅4 H2O (1), which contains a {[Mo3S7(dtp)3]4⋅I} tetramer and (HgI3)−. Compound 1 has been characterized by IR, Rama