Zobrazeno 1 - 10
of 112
pro vyhledávání: '"QD0146"'
Autor:
Targema, Msugh
This thesis presents theoretical investigations that elucidate experimental observations and test theory.\ud Firstly, density functional theory (DFT) is used to determine the mechanism for Pd(0) formation from the pincer palladacycle, PdSCN, with and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=core_ac_uk__::ebe1982adff5e1dc627354dd364ec1ef
Publikováno v:
Inorganic Chemistry. 58:14800-14807
The novel cyaphide complex trans-[Ru(dppe)2Me(CP)] is obtained in excellent yields and exhibits the first instance of con-trolled reactivity of any terminal-cyaphide complex. Its treatment with ZnX2 / PPh3 effects selective metathesis of the methyl m
Autor:
Simon J. Coles, Kieran Griffiths, Annie K. Powell, George E. Kostakis, Irina A. Kühne, Graham J. Tizzard
Publikováno v:
Inorganic Chemistry. 58:2483-2490
Two pentadecanuclear Zn4Ln11 [with Ln = Gd(1) or Dy(2)] coordination clusters, best formulated as {Zn2Ln2}[Ln9]{Zn2}, are presented. The central {Ln9} diabolo core has a {Zn2Ln2} handle motif pulling at two outer Ln ions of the central core via two {
Autor:
Fu-Sheng Guo, Richard A. Layfield, Benjamin M. Day, Yan-Cong Chen, Akseli Mansikkamäki, Ming-Liang Tong
Publikováno v:
Science
Breaking through the nitrogen ceiling Single-molecule magnets could prove useful in miniaturizing a wide variety of devices. However, their application has been severely hindered by the need to cool them to extremely low temperature using liquid heli
Autor:
George E. Kostakis, Edward Loukopoulos
Publikováno v:
Journal of Coordination Chemistry. 71:371-410
This review aims to provide reports of one dimensional (1-D) coordination polymers that have been used as catalysts in various organic reactions in the last decade, covering the literature from 2007 and onwards. The CPs have been mainly categorized i
Publikováno v:
Journal of Organometallic Chemistry. 857:25-33
The mixed sandwich U(III) complex {U[η8-C8H6(1,4-Si(iPr)3)2](Cp*)(THF)} reacts with the organic azides RN3 (R = SiMe3, 1-Ad, BMes2) to afford the corresponding, structurally characterised U(V) imido complexes {U[η8-C8H6(1,4-Si(iPr)3)2](Cp*)(NR)}. I
Autor:
Ying-Ying Zhang, Xiaofan Sun, Bo Li, Hong-Ling Cai, Zhi-Gang Gu, De-Jing Li, Guo Peng, George E. Kostakis
Publikováno v:
Dalton Transactions. 47:17349-17356
The use of 2-naphthalenesulfonate (NAS) ligand in lanthanide chemistry afforded a family of isostructural mononuclear lanthanide complexes with the formula [Ln(NAS)2(H2O)6](NAS)·3H2O [Ln = Tb (1), Dy (2), Er (3), Yb (4)]. Crystallographic studies de
Publikováno v:
Chemical Communications. 54:8830-8833
The activation of C3O2 by the U(III) complex [U(η5-Cp’)3] (Cp’ = C5H4SiMe3) is described. The reaction results in the reductive coupling of three C3O2 units to form a tetranuclear complex with a central cyclobutane-1,3-dione ring, with concomita
Autor:
Albert Escuer, Athanassios C. Tsipis, Simon J. Coles, Graham J. Tizzard, Mohammad Azam, Edward Loukopoulos, Alaa Abdul-Sada, George E. Kostakis, Kieran Griffiths, Stavroula I. Sampani
Publikováno v:
CrystEngComm. 20:1411-1421
The use of the monoanionic Schiff base ligand (E)-4-(2-hydroxybenzylideneamino)-2,3-dimethyl-1-phenyl-1,2-dihydropyrazol-5-one in transition (Co, Ni and Cu) coordination chemistry yields mono-, tetra- and pentanuclear coordination clusters (CCs) with
Autor:
S. Mark Roe, F. Geoffrey N. Cloke, Christopher J. Inman, Alistair S. P. Frey, Alexander F. R. Kilpatrick
Publikováno v:
Organometallics. 36:4539-4545
The new dianionic ligand C6H4{p-C(CH3)2C6H2Me2O–}2(=p-Me2bp), featuring two aryloxide donors and a central arene ring, has been synthesized and used to prepare the mixed-ligand U(III) compound [U(Cp*)(p-Me2bp)], which exhibits an η6interaction wit