Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Priyakumari Chakkingal Parambil"'
Publikováno v:
Chemistry of Materials. 34:3468-3478
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::227810ecdfb9d12a0b837cb0694fbd83
https://doi.org/10.1021/acs.chemmater.2c00306
https://doi.org/10.1021/acs.chemmater.2c00306
Publikováno v:
ChemPhysChem. 24
Lewis acidity trend of boron trihalides is a subject that has received a variety of explanations, and still, the simple π back-bonding based one is believed by most, perhaps because of its simplicity, irrespective of opposing findings. Herein we try
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c788440274a24dffac1fc1a8ac7e2c5
https://doi.org/10.1002/cphc.202200761
https://doi.org/10.1002/cphc.202200761
Inert pair effect—the tendency of s orbital of heavy atoms to stay unreactive, is a consequence of relativistic contraction of the s orbitals. While the manifestations of this, on the reactivity depends on the nature of the substituents, this aspec
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8615cb227103d909f0cdd81e9ce35102
https://doi.org/10.26434/chemrxiv-2022-t04v9
https://doi.org/10.26434/chemrxiv-2022-t04v9
Lewis acidity trend of boron trihalides is a subject that has received a variety of explanations, and still the simple π back-bonding based one is believed by most, perhaps because of its simplicity, irrespective of opposing findings. Herein we try
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ab8c5e3ad90950e4a08845326bbf6bfb
https://doi.org/10.26434/chemrxiv-2022-tls8v
https://doi.org/10.26434/chemrxiv-2022-tls8v
Autor:
Subila Kurukkal Balakrishnan, Priyakumari Chakkingal Parambil, Lothar Houben, Maor Asher, Omer Yaffe, Eran Edri
Publikováno v:
Cell Reports Physical Science. 4:101298
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ea6ea9601973068b0462d9c065b5fab4
https://doi.org/10.1016/j.xcrp.2023.101298
https://doi.org/10.1016/j.xcrp.2023.101298
Publikováno v:
Organometallics. 39:2951-2955
We have developed a strategy for designing planar all-Si and all-P 6π aromatics based on experimentally available building blocks. A Si6 hexagon coordinated by three phosphines at the 1,3,5-positio...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d2e148304cf2f10d9415b63c96042590
https://doi.org/10.1021/acs.organomet.0c00449
https://doi.org/10.1021/acs.organomet.0c00449
Autor:
Aiswarya Abhisek Mohapatra, Yifan Dong, Puttaraju Boregowda, Ashutosh Mohanty, Aditya Sadhanala, Awadhesh Narayan, Chris McNeill, James R Durrant, Satish Patil, Xuechen Jiao, Priyakumari Chakkingal Parambil
An efficient photogeneration of free charge carriers has long been recognized as the paramount challenge in organic photovoltaic (OPV) devices. The low dielectric constant organic semiconductors fall short to reduce strong Coulombic interaction of ti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6e14ac752f9aeba7a653fb92db35f339
https://doi.org/10.26434/chemrxiv.12561965
https://doi.org/10.26434/chemrxiv.12561965
Publikováno v:
Journal of the American Chemical Society. 140:12844-12852
By substituting an ER
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::57cdd3894a96180111ed27ddc7484ace
https://doi.org/10.1021/jacs.8b06141
https://doi.org/10.1021/jacs.8b06141
Publikováno v:
Organometallics. 36:4825-4833
Diplumbenes, R2PbPbR2, are more pyramidalized and trans-bent than the other group 14 analogues and feature long Pb–Pb bonds. A strategy for making these molecules locally planar at Pb, with shorter Pb–Pb separations, starts out from a realization
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2f7b66022559855deb3db9e573d0c2db
https://doi.org/10.1021/acs.organomet.7b00733
https://doi.org/10.1021/acs.organomet.7b00733
Publikováno v:
Journal of the American Chemical Society. 139(20)
We call iodabenzene a cyclic (CH)5I molecule. A planar iodabenzene would have 8 π electrons, a situation best avoided by an out-of-plane distortion to a bird-like geometry. The electronic structure and charge distribution of this molecule resemble t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::735ea9302b2572cf7fea9cb42dc132b3
https://pubmed.ncbi.nlm.nih.gov/28460517
https://pubmed.ncbi.nlm.nih.gov/28460517