The Mechanism of Stereospecific CH Oxidation by Fe(Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containing cis-Labile Exchangeable Sites.

Autor: Prat, Irene¹, Company, Anna¹ anna.company@udg.edu, Postils, Verònica¹, Ribas, Xavi¹, Que, Lawrence², Luis, Josep M.¹ josepm.luis@udg.edu, Costas, Miquel¹ miquel.costas@udg.edu

Publikováno v: Chemistry - A European Journal. May2013, Vol. 19 Issue 21, p6724-6738. 15p.

An Iron Catalyst for Oxidation of Alkyl CH Bonds Showing Enhanced Selectivity for Methylenic Sites.

Autor: Prat, Irene¹, Gómez, Laura¹, Canta, Mercè¹, Ribas, Xavi¹, Costas, Miquel¹ miquel.costas@udg.edu

Publikováno v: Chemistry - A European Journal. Feb2013, Vol. 19 Issue 6, p1908-1913. 6p.

Fe (6-Me-PyTACN)-catalyzed, one-pot oxidative cleavage of methyl oleate and oleic acid into carboxylic acids with H2O2 and NaIO 4

Autor: Spannring, Peter, Prat, Irene, Costas, Miquel, Lutz, Martin, Bruijnincx, Pieter C. A., Weckhuysen, Bert. M., Klein Gebbink, Bert, Organic Chemistry and Catalysis, Inorganic Chemistry and Catalysis, Sub Organic Chemistry and Catalysis, Sub Crystal and Structural Chemistry, Sub Inorganic Chemistry and Catalysis

Publikováno v: © Catalysis Science and Technology, 2014, vol. 4, núm. 3, p. 708-716
Articles publicats (D-Q)
DUGiDocs – Universitat de Girona
instname
Catalysis Science & Technology, 4(3), 708. Royal Society of Chemistry

The first Fe-based catalytic system for the oxidative cleavage of unsaturated fatty acids and esters to carboxylic acids is reported. The system comprises [Fe(OTf)(2)(6-Me-PyTACN)] (2) (6-Me-PyTACN = 1-[(6-methyl-2-pyridyl) methyl]-4,7-dimethyl-1,4,7

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2739422cebc25a7b3952207520e2bfe1
http://hdl.handle.net/10256/10914

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