Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Pradip Kumar Hota"'
Autor:
Shiv Kumar, Ayan Datta, Swadhin K. Mandal, Pradip Kumar Hota, Sreejyothi P, Kalishankar Bhattacharyya
Publikováno v:
Chemistry – A European Journal. 27:11656-11662
In recent years, the applications of low-valent main group compounds have gained momentum in the field of catalysis. Owing to the accessibility of two lone pairs of electrons, NHC-stabilised phosphinidenes have been found to be excellent Lewis bases;
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9133e7557af91fe369c46f1e84a7ad0
https://doi.org/10.1002/chem.202101202
https://doi.org/10.1002/chem.202101202
Publikováno v:
Organometallics. 38:3286-3293
In this study, C(sp2)–H borylation of arenes was accomplished by a nickel catalyst, resulting in good yield. Alkyl and alkoxy arenes were successfully functionalized, affording C(sp2)–H borylated compounds. It was unraveled that the well-defined
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b63a90da89cb3b618914e9440a6f2fa1
https://doi.org/10.1021/acs.organomet.9b00364
https://doi.org/10.1021/acs.organomet.9b00364
Autor:
Swadhin K. Mandal, Gonela Vijaykumar, Pradip Kumar Hota, Rameswar Bhattacharjee, Samaresh Chandra Sau, Ayan Datta, R. Govindarajan, Pavan K. Vardhanapu
Publikováno v:
Chemical Science. 10:1879-1884
This work demonstrates the first-ever completely metal-free approach to the capture of CO2 from air followed by reduction to methoxyborane (which produces methanol on hydrolysis) or sodium formate (which produces formic acid on hydrolysis) under ambi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7b28a87992c8838078062c9afa4f4cce
https://doi.org/10.1039/c8sc03581d
https://doi.org/10.1039/c8sc03581d
Autor:
Pradip Kumar Hota, Samaresh Chandra Sau, Swadhin K. Mandal, Michele Soleilhavoup, Guy Bertrand
Publikováno v:
Chemical Society reviews. 49(4)
Although N-heterocyclic carbenes (NHCs) have been known as ligands for organometallic complexes since the 1960s, these carbenes did not attract considerable attention until Arduengo et al. reported the isolation of a metal-free imidazol-2-ylidene in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a651bf6faea90ad0d64d159877ac7f75
https://pubmed.ncbi.nlm.nih.gov/31998907
https://pubmed.ncbi.nlm.nih.gov/31998907
Publikováno v:
ACS Catalysis. 8:11999-12003
This study reports the metal-free formylation of amides using carbon dioxide under ambient conditions. An abnormal N-heterocyclic carbene (aNHC) acts as an efficient catalyst for the formylation of amides in the presence of hydrosilane at room temper
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::022016b07b8eb1c169cb6197dac9a8ca
https://doi.org/10.1021/acscatal.8b04023
https://doi.org/10.1021/acscatal.8b04023
Publikováno v:
Organometallics. 36:4422-4431
Hydroarylation of alkyne was reported by Fujiwara nearly two decades back. Interestingly, this reaction does not proceed in the absence of trifluoroacetic acid; however, the exact role of TFA has not been unambiguously established, in particular with
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::858ce1ad354878598ebfce6834704d7c
https://doi.org/10.1021/acs.organomet.7b00649
https://doi.org/10.1021/acs.organomet.7b00649
Autor:
Pradip Kumar Hota, Gonela Vijaykumar, Samaresh Chandra Sau, Swadhin K. Mandal, Pavan K. Vardhanapu, Jasimuddin Ahmed, Sreejyothi P
Publikováno v:
European Journal of Organic Chemistry. 2017:1004-1011
Herein, we report a versatile catalytic system for the direct C–H arylation of heteroarenes with activated aryl chloride substrates. The catalyst works successfully for a variety of heteroarenes and aryl chloride coupling partners under very low ca
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f8722d050c7c28836e3bcbe98f52b986
https://doi.org/10.1002/ejoc.201601218
https://doi.org/10.1002/ejoc.201601218
Publikováno v:
Chemical communications (Cambridge, England). 56(4)
Herein we report an abnormal N-heterocyclic carbene catalyzed dehydration of primary amides in the presence of a silane. This process bypasses the energy demanding 1,2-siloxane elimination step usually required for metal/silane catalyzed reactions. A
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3155f35e863ebde9741dc920143e6088
https://pubmed.ncbi.nlm.nih.gov/31830152
https://pubmed.ncbi.nlm.nih.gov/31830152
Publikováno v:
Organometallics. 35:2930-2937
A base-metal, Fe(0)-catalyzed hydrosilylation of imines to obtain amines is reported here which outperforms its noble-metal congeners with the highest TON of 17000. The catalyst, (aNHC)Fe(CO)4, works under very mild conditions, with extremely low cat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7d77fe276cd64ffeb6541259c8d48404
https://doi.org/10.1021/acs.organomet.6b00478
https://doi.org/10.1021/acs.organomet.6b00478
Autor:
Jasimuddin Ahmed, Justin P. Johnpeter, Swadhin K. Mandal, Pradip Kumar Hota, Samaresh Chandra Sau, Bhagat Singh, Rupankar Paira
Publikováno v:
The Journal of Organic Chemistry. 81:2432-2441
Open-shell phenalenyl chemistry has widely been explored in the last five decades demonstrating its potential in various applications including molecular switch, spin memory device, molecular battery, cathode material, etc. In this article, we have e
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8294f47e37119b764fb96c21f5c30cfe
https://doi.org/10.1021/acs.joc.6b00002
https://doi.org/10.1021/acs.joc.6b00002