Výsledky vyhledávání - "Prabha, Vadivelu"

Akademický článek

In-situ interfacial compatibilization via edge-sulfurated few layer graphene during the formation of crosslinked graphene-rubber nanocomposites

Autor: Sangeeth Krishnan, Maya M.G, Akhil Das, Suja Bhargavan, Krithika Ganesan, Swaminathan Sivaram, Prabha Vadivelu, Lakshminarayanan Ragupathy

Publikováno v: Scientific Reports, Vol 12, Iss 1, Pp 1-12 (2022)

Abstract Herein, we report various physico-chemical approaches to probe the nature of the interface between few layers graphene (FLG) and carboxylated nitrile rubber (XNBR) nanocomposites prepared through efficient blending of XNBR latex with an aque

Externí odkaz: https://doaj.org/article/58c91cfe7ab94be88d3daf79132a2780

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N-2,2,2-trifluoroethylisatinketimine as a 1,2-dipolarophile for [3+2]- addition to access optically pure spirothiazolidine oxindoles

Autor: Madavi S. Prasad, Sankar Bharani, Sivaprakash Murugesan, Prabha Vadivelu, Durairajan Siva Sundara Kumar, L Raju Chowhan

Publikováno v: Organic & Biomolecular Chemistry.

The first report on using N-2,2,2-trifluoroethylisatinketimine as 1,2-dipolarophile for [3+2]-addition and the first asymmetric synthesis of N-2,2,2-trifluoroethylspirothiazolidine oxindoles is described. The organocatalyzed asymmetric [3+2]-addition

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::44d22cfd60200bc6c208bcd184de5fd5
https://doi.org/10.1039/d3ob00685a

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A Density Functional Theory Study on Comparing the Reactivity of [Mn(13-TMC)(OOH)]2+ and [Mn(13-TMC)(O2)]+ for the Sulfoxidation of Thioanisole: Elucidation of Substrate and Non-Redox Metal Ion Effects

Autor: Prabha Vadivelu, Ilakya Kaliyaperumal, Krithika Ganesan

Publikováno v: Inorganic Chemistry. 60:13615-13625

The reactivities of [Mn(13-TMC)(OOH)]2+ (1) and [Mn(13-TMC)(O2)]+ (2) in the sulfoxidation of thioanisole have been compared using density functional theory methods. The orientation of the 13-TMC ligand and substrate and non-redox metal ion effects h

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4d619b7aea1917c88b93021d3c03e45c
https://doi.org/10.1021/acs.inorgchem.1c01915

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Facile, environmentally benign and scalable approach to produce pristine few layers graphene suitable for preparing biocompatible polymer nanocomposites

Autor: Gejo, George, Suja Bhargavan, Sisupal, Teenu, Tomy, Alaganandam, Kumaran, Prabha, Vadivelu, Vemparthan, Suvekbala, Swaminathan, Sivaram, Lakshminarayanan, Ragupathy

Publikováno v: Scientific Reports, Vol 8, Iss 1, Pp 1-14 (2018)
Scientific Reports

The success of developing graphene based biomaterials depends on its ease of synthesis, use of environmentally benign methods and low toxicity of the chemicals involved as well as biocompatibility of the final products/devices. We report, herein, a s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid_dedup__::d3d1c31d692d4224c48e9cb05261b783
http://link.springer.com/article/10.1038/s41598-018-28560-1

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Computational prediction of cyclometalated IrIII, RhIII and CoIII amido complexes to capture up to three CO2 molecules

Autor: Prabha Vadivelu, Cherumuttathu H. Suresh

Publikováno v: Dalton Transactions. 44:16847-16853

An organometallic complex showing the ability to capture up to three CO2 molecules is unprecedented in chemistry while with convincing theoretical evidence we show that [(CH3)2PCH2NH2] (pcn) based cyclometalated Ir(iii), Rh(iii) and Co(iii) amido com

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0cc62fdec292d5f0ba072cd866cb151
https://doi.org/10.1039/c5dt02514a

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Novel nickel(ii) complexes of sterically modified linear N4 ligands: effect of ligand stereoelectronic factors and solvent of coordination on nickel(ii) spin-state and catalytic alkane hydroxylation

Autor: Prabha Vadivelu, Mallayan Palaniandavar, Muniyandi Sankaralingam

Publikováno v: Dalton transactions (Cambridge, England : 2003). 46(22)

A series of Ni(II) complexes of the types [Ni(L)(CH3CN)2](BPh4)21–3, 5 and [Ni(L4)](BPh4)24, where L = N,N′-bis(2-pyrid-2-ylmethyl)-1,4-diazepane (L1), N-(6-methylpyrid-2-ylmethyl)-N′-(pyrid-2-ylmethyl)-1,4-diazepane (L2), N,N′-bis(6-methyl-2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::33feb67bf8bb58c753dda002eecb1c2e
https://pubmed.ncbi.nlm.nih.gov/28418046

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Nickel(II) Complexes of Pentadentate N5 Ligands as Catalysts for Alkane Hydroxylation by Usingm-CPBA as Oxidant: A Combined Experimental and Computational Study

Autor: Mani Balamurugan, Prabha Vadivelu, Mallayan Palaniandavar, Cherumuttathu H. Suresh, Muniyandi Sankaralingam

Publikováno v: Chemistry - A European Journal. 20:11346-11361

A new family of nickel(II) complexes of the type [Ni(L)(CH(3)CN)](BPh(4))(2), where L=N-methyl-N,N',N'-tris(pyrid-2-ylmethyl)-ethylenediamine (L1, 1), N-benzyl-N,N',N'-tris(pyrid-2-yl-methyl)-ethylenediamine (L2, 2), N-methyl-N,N'-bis(pyrid-2-ylmethy

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4f6be23c0b19bf26c301b3831209f67e
https://doi.org/10.1002/chem.201402391

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