Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes

Autor: Joaquín López-Serrano, Laura L. Santos, Andrés Suárez, Isabel Ortega-Lepe, Andrea Rossin, Eleuterio Álvarez, Nuria Rendón, Práxedes Sánchez

Publikováno v: Inorganic chemistry (Online) 60 (2021): 18490–18502. doi:10.1021/acs.inorgchem.1c03056
info:cnr-pdr/source/autori:Isabel Ortega-Lepe, Andrea Rossin, Praxedes Sanchez, Laura L. Santos, Nuria Rendon, Eleuterio A?lvarez, Joaquin Lopez-Serrano, and Andres Suarez/titolo:Ammonia-Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes/doi:10.1021%2Facs.inorgchem.1c03056/rivista:Inorganic chemistry (Online)/anno:2021/pagina_da:18490/pagina_a:18502/intervallo_pagine:18490–18502/volume:60
Digital.CSIC. Repositorio Institucional del CSIC
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Inorganic Chemistry

Metal complexes incorporating proton-responsive ligands have been proved to be superior catalysts in reactions involving the H2 molecule. In this contribution, a series of IrIII complexes based on lutidine-derived CNNH pincers containing N-heterocycl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::101eb1dd72aee79444d4541c2d454051
https://doi.org/10.1021/acs.inorgchem.1c03056

Catalytic Nitrous Oxide Reduction with H

Autor: Isabel, Ortega-Lepe, Práxedes, Sánchez, Laura L, Santos, Patricia, Lara, Nuria, Rendón, Joaquín, López-Serrano, Verónica, Salazar-Pereda, Eleuterio, Álvarez, Margarita, Paneque, Andrés, Suárez

Publikováno v: Inorganic chemistry. 61(46)

Reduction of nitrous oxide (N

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::f4cc9857b9dc9d6212f50fe85b1a5216
https://pubmed.ncbi.nlm.nih.gov/36346983

Electrophilic activation of alkynes promoted by a cationic alkylidene complex of Pt(II)

Autor: María M. Alcaide, Práxedes Sánchez, Eleuterio Álvarez, Celia Maya, Joaquín López-Serrano, Riccardo Peloso

Publikováno v: Dalton transactions (Cambridge, England : 2003). 51(15)

Pt(II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic activation of the CC bond and its insertion into the platinacyclic fragment of 1a that contains the carbene functionality. DFT

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ff6f0273efb032b0e978b618043f5da3
https://pubmed.ncbi.nlm.nih.gov/35352740

Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Autor: Práxedes Sánchez, Laura L. Santos, Eleuterio Álvarez, Andrés Suárez, Martín Hernández-Juárez, Nuria Rendón, Margarita Paneque, Joaquín López-Serrano

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
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Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f0e7b49efc1927b3d2b65dbe4f9d5e96
http://hdl.handle.net/10261/221900

Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity

Autor: Margarita Paneque, Joaquín López-Serrano, Práxedes Sánchez, Eleuterio Álvarez, Nuria Rendón, Andrés Suárez, Martín Hernández-Juárez

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
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Iridium complexes based on deprotonated lutidine-derived CNP* pincers 2a/2b selectively catalyzed the hydroboration of CO2 under mild conditions (1–2 bar CO2, 30 °C) to methoxyborane using HBcat (TOF up to 56 h−1) and to the formate level with H

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::585b66c53f27123f8194a88e8f1b51f5
https://doi.org/10.1039/c8dt03951h