Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Pit van Bonn"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 20, Iss 1, Pp 2799-2805 (2024)
We present a mechanochemical synthesis of difluoromethyl enol ethers. Utilizing an in situ generation of difluorocarbenes, ketones are efficiently converted to the target products under solvent-free conditions. The reactions proceed at room temperatu
Externí odkaz:
https://doaj.org/article/07f0a29822dd4410bdd6929dafaa0064
Publikováno v:
CCS Chemistry. :1-22
Publikováno v:
Angewandte Chemie.
Publikováno v:
ACS Sustainable Chemistry & Engineering. 10:1361-1366
Autor:
Carsten Bolm, Pit van Bonn
Publikováno v:
Synlett. 33:893-897
A mechanochemical synthesis of diarylethynes from aryl iodides and calcium carbide as acetylene source is reported. The reaction is catalyzed by a palladium catalyst in the presence of copper salt, base, and ethanol as liquid assisting grinding (LAG)
Publikováno v:
Chemistry – A European Journal. 26:2576-2580
Esters and amides were mechanochemically prepared by palladium-catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real-ti
Publikováno v:
Angewandte Chemie / International edition 59(1), 215-220 (2020). doi:10.1002/anie.201909035
Angewandte Chemie 132(1), 221-226 (2020). doi:10.1002/ange.201909035
Angewandte Chemie (International Ed. in English)
Angewandte Chemie 132(1), 221-226 (2020). doi:10.1002/ange.201909035
Angewandte Chemie (International Ed. in English)
Highly selective β‐methylation of alcohols was achieved using an earth‐abundant first row transition metal in the air stable molecular manganese complex [Mn(CO)2Br[HN(C2H4PiPr2)2]] 1 ([HN(C2H4PiPr2)2]=MACHO‐iPr). The reaction requires only low
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Esters and amides were mechanochemically prepared by palladium‐catalyzed carbonylative reactions of aryl iodides by using molybdenum hexacarbonyl as a convenient solid carbonyl source and avoiding a direct handling of gaseous carbon monoxide. Real