Zobrazeno 1 - 10
of 49
pro vyhledávání: '"Piotr Gzil"'
Publikováno v:
International Journal of Computational Methods. :551-574
A newly developed computational fluid dynamics method for simulating chromatographic adsorption is presented. This well-validated software package takes adsorption reactions as well as internal porosity into account to explain differences caused by t
Publikováno v:
Journal of Chromatography A. 1188:171-188
Numerically solving the effective diffusion in a simplified representation of a chromatographic bed, it was found that the B-term expressions that have up to now been used in the literature, and which can all be reduced to either Deff=(gamma mDm+k'ga
Publikováno v:
Journal of Chromatography A. 1146:193-201
Using a set of experimentally determined plate height data obtained on three commercial high-temperature HPLC supports, and evaluating their isocratic separation speed potential under the application of a set of instrumental constraints, a qualitativ
Publikováno v:
Journal of Chromatography A, 1130(1), 108-114. Elsevier
The present study concerns the problem of finding appropriate experimental conditions and comparison criteria to assess the kinetic performance of LC supports with different sizes or morphologies. A general procedure, based on evaluating each support
Publikováno v:
Vrije Universiteit Brussel
Using kinetic plots to analyse the performance of some of the best silica monoliths found in the literature shows that the current generation of silica monoliths outperform particulate beds only in the high plate-number region (roughly N > 40000). Th
Autor:
Jan De Smet, Achim Van Theemsche, Calin Dan, Nico Vervoort, Johan Deconinck, Gert Desmet, Piotr Gzil
Publikováno v:
Vrije Universiteit Brussel
Using a well-validated computational fluid dynamics simulation method, based on a multi-ion transport model, a detailed analysis of the differences in band broadening between pressure-driven (PD) and electrically driven (ED) flows through perfectly o
Publikováno v:
Journal of Chromatography A. 1030:53-62
The chromatographic performance of several straightforward two-dimensional etched packed bed column lay-outs (equilaterally staggered arrays of, respectively, circular, hexagonal, and diamond-like pillars) has been compared using commercial computati
Publikováno v:
Journal of Chromatography A. 991:169-188
A theoretical calculation of the separation performance of a (hypothetical) micro-structured monolithic LC column is presented, confirming that the polydispersity effect in parallel bundle columns can theoretically be eliminated to a very large exten
Publikováno v:
Vrije Universiteit Brussel
It is only by developing specially designed injection and detection systems that shear-driven chromatography can become a viable alternative to HPLC. In the present paper, a dedicated zero dead-volume injection procedure is presented with which sampl
Publikováno v:
Vrije Universiteit Brussel
Numerically solving the effective diffusion in a simplified representation of a chromatographic bed, it was found that the B-term expressions that have up to now been used in the literature, and which can all be reduced to either Deff=(gamma mDm+k'ga
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid_dedup__::8b5e1767d81918cdabde83f55d80c83f
https://hdl.handle.net/20.500.14017/5abf97c4-d917-47da-bed0-33cd5a0bff07
https://hdl.handle.net/20.500.14017/5abf97c4-d917-47da-bed0-33cd5a0bff07