Zobrazeno 1 - 10
of 28
pro vyhledávání: '"Piotr Buchalski"'
Publikováno v:
Dalton Transactions. 46:3805-3808
A remarkable nickelacycle has been synthesised via olefin metathesis of the α,ω-diene complex [Ni(η5-C5H4R)(Br)(NHC)] (R = C(CH3)2CH2CHCH2, NHC = 1-(6-hexenyl)-3-(2,4,6-trimethylphenyl)-imidazol-2-ylidene). Single-crystal X-ray analysis reveals a
Autor:
Piotr Buchalski, Aleksander Shkurenko, Karol Molga, Włodzimierz Buchowicz, Kinga Suwińska, Jan Gustowski, Roman Pacholski
Publikováno v:
Journal of Organometallic Chemistry. :40-45
In this paper we present the synthesis and characterisation of novel bisnickelacyclic complexes. We carried out the reaction between 2,2′,2″,5′-tetralithio-1,1′,4′,1″-terphenyl and nickelocene in which bisnickelacyclic–dilithium complex
Publikováno v:
Journal of Organometallic Chemistry. 785:26-31
In this paper we describe the syntheses and characterization of novel axially chiral metallacyclic complexes. Contrary to previously described synthesis of 9-nickelafluorenyllithium complexes, reaction of dilithium ligand afforded nickelacyclic analo
Autor:
Aleksander Shkurenko, Piotr Buchalski, Kinga Suwińska, Krzysztof Chodkiewicz, Włodzimierz Buchowicz, Roman Pacholski
Publikováno v:
Dalton Transactions. 44:7169-7176
Investigation of the properties of carbene complexes is one of the most important fields of modern coordination chemistry. In this paper, we propose the convenient synthesis of NHC-nickel compounds. The 9-nickelafluorenyllithium complex reacts with i
Autor:
Patryk Jadach, Lucjan B. Jerzykiewicz, Piotr Buchalski, Antoni Pietrzykowski, Kinga Suwińska, Jarosław Sadło
Publikováno v:
Organometallics. 27:3618-3621
Reactions of 9-nickelafluorenyllithium complexes with water were carried out. Trinickel clusters with aryne ligands were formed (via aromatic C−H bond activation by a nickel atom), whose crystal and molecular structures were determined by single-cr
Publikováno v:
Organometallics. 27:3316-3319
(9-Nickelafluorenyl)lithium was found to react with Ni(II) and Co(II) salts to form novel complexes in which the Ni or Co central metal atom is bonded to two nickelafluorenyl ligands. The crystal and molecular structures of the products were determin
Publikováno v:
Organometallics. 27:2346-2349
A novel lithium biphenyl-2,2′-diyl(cyclopentadienyl)nickelate compound (9-nickelafluorenyllithium complex), (η2-(1-(η5-cyclopentadienyl))-1-nickelafluorenyl)lithium(diethyl ether)2 (1), was prepared in the reaction between 2,2′-dilithiobiphenyl
Autor:
Jolanta Zbrzezna, Piero Zanello, Fabrizia Fabrizi de Biani, Fulvio Rossi, Serena Losi, Franco Laschi, Katarzyna Piwowar, Antoni Pietrzykowski, Stanisa̵w Pasynkiewicz, Piotr Buchalski, Kinga Burakowska, Lucjan B. Jerzykiewicz, and Kinga Suwińska
Publikováno v:
Inorganic Chemistry. 46:10659-10669
Following previous reports on the synthesis and structure of different nickelacyclic complexes analogues of nickelocene, we now deal with the new metallacyclic compounds (η5-R-cyclopentadienyl){η4-[1-(η5-R-cyclopentadienyl)]-2,3,4,5-tetraphenyl-1-
Autor:
Piotr Buchalski, Janusz Lipkowski, Stanisław Pasynkiewicz, Marek Cypryk, Antoni Pietrzykowski
Publikováno v:
Journal of Organometallic Chemistry. 691:5825-5830
A novel tetrahedral (μ3-alkylidyne)tetranickel cluster (NiCp)4(μ3-C(CH2)4CH3) (4) was obtained in the reaction of nickelocene with potassium and 1-hexene. Compound 4 was characterised by means of MS and X-ray diffraction analysis. It crystallizes i
Autor:
Monika Zdziemborska, Piotr Buchalski, Stanisław Pasynkiewicz, Kinga Suwinska, Andrzej Kozioł, Antoni Pietrzykowski
Publikováno v:
Journal of Organometallic Chemistry. 691:4080-4085
New binuclear nickelacyclic compounds 1 (η 5 -pentamethylcyclopentadienyl)(η 3 -(1-(η 5 -pentamethylcyclopentadienyl))-1-nickelafluorenyl)nickel and 2 (η 5 -pentamethylcyclopentadienyl)(η 3 -(1-(η 5 -pentamethylcyclopentadienyl))-2-phenyl-3-eth