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Autor: Pilgrim, CD, Casey, WH, Walton, JH

Publikováno v: eMagRes, vol 8, iss 2

High-pressure NMR has been in existence or 65 years and has evolved to be an essential tool for many disciplines. High-pressure NMR is useful both for determining standard thermodynamic properties and for assigning mechanisms of aqueous ligand-exchan

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______325::53da8b397ddb738da31aa3f10ed6241a
https://escholarship.org/uc/item/4867q0dk

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27Al MQMAS of the δ-Al13-Keggin

Autor: Pilgrim, CD, Callahan, JR, Colla, CA, Ohlin, CA, Mason, HE, Casey, WH

Publikováno v: Dalton transactions (Cambridge, England : 2003), vol 46, iss 7

One-dimensional 27Al, 23Na Magic-Angle-Spinning (MAS) NMR and 27Al Multiple-Quantum Magic-Angle-Spinning NMR (MQMAS) measurements are reported for the δ-isomer of the Al13 Keggin structure at high spinning speed and 14.1 T field. Values for the CQ a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::04c71fd06c460d614e65cfd2619ba76a
https://escholarship.org/uc/item/9d91960t

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Isomerization of Keggin Al13 Ions Followed by Diffusion Rates

Autor: Oliveri, AF, Colla, CA, Perkins, CK, Akhavantabib, N, Callahan, JR, Pilgrim, CD, Smart, SE, Cheong, PHY, Pan, L, Casey, WH

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany), vol 22, iss 52
Chemistry-A European Journal, vol 22, iss 52

The solution chemistry of aluminum has long interested scientists due to its relevance to materials chemistry and geochemistry. The dynamic behavior of large aluminum-oxo-hydroxo clusters, specifically [Al13 O4 (OH)24 (H2 O)12 ]7+ (Al13 ), is the foc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::2c1bcab2fb7c1b2f614557939609ac09
https://escholarship.org/uc/item/4m57p4ff

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Akademický článek

Radiolytic evaluation of a new technetium redox control reagent for advanced used nuclear fuel separations.

Autor: Dang AN; Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Boulevard, Long Beach California, 90840-9507, USA. stephen.mezyk@csulb.edu., Rogalski MH; Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Boulevard, Long Beach California, 90840-9507, USA. stephen.mezyk@csulb.edu., Pilgrim CD; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Freemont Ave., P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov., Wilbanks JR; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Freemont Ave., P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov., Peterman DR; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Freemont Ave., P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov., Carrie JD; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Freemont Ave., P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov., Zalupski PR; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Freemont Ave., P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov., Mezyk SP; Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Boulevard, Long Beach California, 90840-9507, USA. stephen.mezyk@csulb.edu., Horne GP; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Freemont Ave., P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.holmbeck@inl.gov.

Publikováno v: Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2024 Jan 31; Vol. 26 (5), pp. 4039-4046. Date of Electronic Publication: 2024 Jan 31.

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Akademický článek

Tuning aminopolycarboxylate chelators for efficient complexation of trivalent actinides.

Autor: Pilgrim CD; Aqueous Separations and Radiochemistry, Idaho National Laboratory, Idaho Falls, ID, 83415, USA. corey.pilgrim@inl.gov.; Glenn T. Seaborg Institute, Idaho National Laboratory, Idaho Falls, ID, 83415, USA. corey.pilgrim@inl.gov., Grimes TS; Aqueous Separations and Radiochemistry, Idaho National Laboratory, Idaho Falls, ID, 83415, USA., Smith C; Aqueous Separations and Radiochemistry, Idaho National Laboratory, Idaho Falls, ID, 83415, USA., Heathman CR; Aqueous Separations and Radiochemistry, Idaho National Laboratory, Idaho Falls, ID, 83415, USA., Mathew J; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA., Jansone-Popova S; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA. jansonepopos@ornl.gov., Roy S; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA., Ray D; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA., Bryantsev VS; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA., Zalupski PR; Aqueous Separations and Radiochemistry, Idaho National Laboratory, Idaho Falls, ID, 83415, USA. peter.zalupski@inl.gov.

Publikováno v: Scientific reports [Sci Rep] 2023 Oct 19; Vol. 13 (1), pp. 17855. Date of Electronic Publication: 2023 Oct 19.

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Akademický článek

Gamma Radiation-Induced Degradation of Acetohydroxamic Acid (AHA) in Aqueous Nitrate and Nitric Acid Solutions Evaluated by Multiscale Modelling.

Autor: Conrad JK; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Fremont Ave., 83415, Idaho Falls, ID, USA., Mezyk SP; Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Blvd, 90840, Long Beach, CA, USA., Isherwood LH; Dalton Cumbrian Facility, The University of Manchester, West Lakes Science Park, CA24 3HA, Moor Row, U. K.; Department of Chemistry, The University of Manchester, Oxford Rd, M13 9PL, Manchester, U.K., Baidak A; Dalton Cumbrian Facility, The University of Manchester, West Lakes Science Park, CA24 3HA, Moor Row, U. K.; Department of Chemistry, The University of Manchester, Oxford Rd, M13 9PL, Manchester, U.K., Pilgrim CD; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Fremont Ave., 83415, Idaho Falls, ID, USA., Whittaker D; National Nuclear Laboratory, Central Laboratory, Sellafield, Seascale, CA20 1PG, Cumbria, U.K., Orr RM; National Nuclear Laboratory, Central Laboratory, Sellafield, Seascale, CA20 1PG, Cumbria, U.K., Pimblott SM; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Fremont Ave., 83415, Idaho Falls, ID, USA., Horne GP; Center for Radiation Chemistry Research, Idaho National Laboratory, 1955 N. Fremont Ave., 83415, Idaho Falls, ID, USA.

Publikováno v: Chemphyschem : a European journal of chemical physics and physical chemistry [Chemphyschem] 2023 Mar 01; Vol. 24 (5), pp. e202200749. Date of Electronic Publication: 2022 Dec 05.

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Akademický článek

Facile nanoplastics formation from macro and microplastics in aqueous media.

Autor: Peller JR; Department of Chemistry, 1710 Chapel Drive, Valparaiso University, Valparaiso, IN, 46383, USA. Electronic address: julie.peller@valpo.edu., Mezyk SP; Department of Chemistry and Biochemistry, California State University, Long Beach, CA, 90804, USA., Shidler S; Renishaw, Inc., West Dundee, IL, 60118, USA., Castleman J; Department of Chemistry, 1710 Chapel Drive, Valparaiso University, Valparaiso, IN, 46383, USA., Kaiser S; Department of Chemistry, 1710 Chapel Drive, Valparaiso University, Valparaiso, IN, 46383, USA., Faulkner RF; Department of Chemistry and Biochemistry, California State University, Long Beach, CA, 90804, USA., Pilgrim CD; Center for Radiation Chemistry Research, Idaho National Laboratory, Idaho Falls, ID, P.O. Box 1625, 83415, USA., Wilson A; Department of Chemistry, 1710 Chapel Drive, Valparaiso University, Valparaiso, IN, 46383, USA., Martens S; Department of Chemistry, 1710 Chapel Drive, Valparaiso University, Valparaiso, IN, 46383, USA., Horne GP; Center for Radiation Chemistry Research, Idaho National Laboratory, Idaho Falls, ID, P.O. Box 1625, 83415, USA.

Publikováno v: Environmental pollution (Barking, Essex : 1987) [Environ Pollut] 2022 Nov 15; Vol. 313, pp. 120171. Date of Electronic Publication: 2022 Sep 13.

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Akademický článek

Radiolytic Gas Production from Aluminum Coupons (Alloy 1100 and 6061) in Helium Environments-Assessing the Extended Storage of Aluminum Clad Spent Nuclear Fuel.

Autor: Conrad JK; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA., Pu X; Characterization and Post Irradiation Examination, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA., Khanolkar A; Condensed Matter and Materials Physics Group, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA., Copeland-Johnson TM; Characterization and Post Irradiation Examination, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA.; Glenn T. Seaborg Institute, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA., Pilgrim CD; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA., Wilbanks JR; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA., Parker-Quaife EH; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA., Horne GP; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415, USA.

Publikováno v: Materials (Basel, Switzerland) [Materials (Basel)] 2022 Oct 19; Vol. 15 (20). Date of Electronic Publication: 2022 Oct 19.

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Akademický článek

Multiscale modelling of the radical-induced chemistry of acetohydroxamic acid in aqueous solution.

Autor: Conrad JK; Center for Radiation Chemistry Research, Idaho National Laboratory 1955 N. Fremont Ave. Idaho Falls ID 83415 USA jacy.conrad@inl.gov gregory.horne@inl.gov., Pilgrim CD; Center for Radiation Chemistry Research, Idaho National Laboratory 1955 N. Fremont Ave. Idaho Falls ID 83415 USA jacy.conrad@inl.gov gregory.horne@inl.gov., Pimblott SM; Center for Radiation Chemistry Research, Idaho National Laboratory 1955 N. Fremont Ave. Idaho Falls ID 83415 USA jacy.conrad@inl.gov gregory.horne@inl.gov., Mezyk SP; Department of Chemistry and Biochemistry, California State University Long Beach 1250 Bellflower Blvd. Long Beach CA 90840 USA., Horne GP; Center for Radiation Chemistry Research, Idaho National Laboratory 1955 N. Fremont Ave. Idaho Falls ID 83415 USA jacy.conrad@inl.gov gregory.horne@inl.gov.

Publikováno v: RSC advances [RSC Adv] 2022 Oct 18; Vol. 12 (46), pp. 29757-29766. Date of Electronic Publication: 2022 Oct 18 (Print Publication: 2022).

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Akademický článek

Influence of uranyl complexation on the reaction kinetics of the dodecane radical cation with used nuclear fuel extraction ligands (TBP, DEHBA, and DEHiBA).

Autor: Celis Barros C; Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA. ccelisbarros@fsu.edu., Pilgrim CD; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.p.horne@inl.gov., Cook AR; Department of Chemistry, Brookhaven National Laboratory, Upton, New York, 11973, USA., Mezyk SP; Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Boulevard, Long Beach, California, 90840-9507, USA., Grimes TS; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.p.horne@inl.gov., Horne GP; Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID, 83415, USA. gregory.p.horne@inl.gov.

Publikováno v: Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2021 Nov 10; Vol. 23 (43), pp. 24589-24597. Date of Electronic Publication: 2021 Nov 10.

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