Electrochemical quinuclidine-mediated C–H activation: Intermediates and mechanism

Autor: Filip Vorobjov, Gilles De Smet, Nick Daems, H.Y. Vincent Ching, Pieter Leveque, Bert U.W. Maes, Tom Breugelmans

Publikováno v: Journal of electroanalytical chemistry : an international journal devoted to all aspects of electrode kynetics, interfacial structure, properties of electrolytes, colloid and biological electrochemistry.

The reaction mechanism of quinuclidine mediated C-H oxidation of unactivated C-H bonds has been elucidated. In-situ cathodically generated H2O2 was shown to diffuse to the anode where it is oxidized and participates in the ketonization reaction. Furt

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::06d3ca8674e2b7b14c10f43049898c46
https://doi.org/10.1016/j.jelechem.2022.116835