Continuous-flow processes for the catalytic partial hydrogenation reaction of alkynes

Autor: Carmen Moreno-Marrodan, Francesca Liguori, Pierluigi Barbaro

Publikováno v: Beilstein Journal of Organic Chemistry, Vol 13, Iss 1, Pp 734-754 (2017)

The catalytic partial hydrogenation of substituted alkynes to alkenes is a process of high importance in the manufacture of several market chemicals. The present paper shortly reviews the heterogeneous catalytic systems engineered for this reaction u

Externí odkaz: https://doaj.org/article/0424834672d24c9a9f3d4701a98e2ae3

Sustainable processes for the catalytic synthesis of safer chemical substitutes of N-methyl-2-pyrrolidone

Autor: Carmen Moreno-Marrodan, Pierluigi Barbaro, Francesca Liguori

Publikováno v: Molecular catalysis 466 (2019): 60–69. doi:10.1016/j.mcat.2019.01.014
info:cnr-pdr/source/autori:Moreno-Marrodan C.; Liguori F.; Barbaro P./titolo:Sustainable processes for the catalytic synthesis of safer chemical substitutes of N-methyl-2-pyrrolidone/doi:10.1016%2Fj.mcat.2019.01.014/rivista:Molecular catalysis/anno:2019/pagina_da:60/pagina_a:69/intervallo_pagine:60–69/volume:466

N-methyl-2-pyrrolidone (NMP) is a chemical widely used as solvent in several industrial applications. However, many studies and regulations, including REACH, have indicated NMP as a potential toxic agent. Therefore, functional substitutes with high m

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::58f0d42b04dece2738cbadd779a7a241
https://doi.org/10.1016/j.mcat.2019.01.014

Liquid-phase synthesis of methyl isobutyl ketone over bifunctional heterogeneous catalysts comprising cross-linked perfluorinated sulfonic acid Aquivion polymers and supported Pd nanoparticles

Autor: Francesca Liguori, Nicola Calisi, Pierluigi Barbaro, Claudio Oldani, Laura Capozzoli

Publikováno v: Applied catalysis. A, General
610 (2021). doi:10.1016/j.apcata.2020.117957
info:cnr-pdr/source/autori:Liguori, Francesca; Oldani, Claudio; Capozzoli, Laura; Calisi, Nicola; Barbaro, Pierluigi/titolo:Liquid-phase synthesis of methyl isobutyl ketone over bifunctional heterogeneous catalysts comprising cross-linked perfluorinated sulfonic acid Aquivion polymers and supported Pd nanoparticles/doi:10.1016%2Fj.apcata.2020.117957/rivista:Applied catalysis. A, General (Print)/anno:2021/pagina_da:/pagina_a:/intervallo_pagine:/volume:610

The solvent-free hydrogenation reaction of acetone over bifunctional heterogeneous catalysts, comprising cross-linked perfluorosulfonic acid (PFSA) resins and supported Pd nanoparticles, was investigated in the liquid phase under batch conditions. A

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd41a38c2e8b01bba6e565e74fcbe523
https://publications.cnr.it/doc/439807

Low‐Temperature Continuous‐Flow Dehydration of Xylose Over Water‐Tolerant Niobia–Titania Heterogeneous Catalysts

Autor: Stefano Caporali, Carmen Moreno-Marrodan, Pierluigi Barbaro, Filippo Bossola

Publikováno v: ChemSusChem (Weinh., Print) 11 (2018): 3649–3660. doi:10.1002/cssc.201801414
info:cnr-pdr/source/autori:Moreno-Marrodan C.; Barbaro P.; Caporali S.; Bossola F./titolo:Low-Temperature Continuous-Flow Dehydration of Xylose Over Water-Tolerant Niobia-Titania Heterogeneous Catalysts/doi:10.1002%2Fcssc.201801414/rivista:ChemSusChem (Weinh., Print)/anno:2018/pagina_da:3649/pagina_a:3660/intervallo_pagine:3649–3660/volume:11

The sustainable conversion of vegetable biomass-derived feeds to useful chemicals requires innovative routes meeting environmental and economical criteria. The approach herein pursued is the synthesis of water-tolerant, unconventional solid acid mono

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b33a3878a1a595316bd1016e0a75dbb8
https://doi.org/10.1002/cssc.201801414

Unconventional Pd@Sulfonated Silica Monoliths Catalysts for Selective Partial Hydrogenation Reactions under Continuous Flow

Autor: Vladimiro Dal Santo, Elisa Passaglia, Anne Galarneau, Francesca Liguori, Bilel Said, Alessandro Feis, Pierluigi Barbaro

Publikováno v: ChemCatChem
ChemCatChem, Wiley, 2017, 9 (16), pp.3245-3258. ⟨10.1002/cctc.201700381⟩
(2017): 3245–3258. doi:10.1002/cctc.201700381
info:cnr-pdr/source/autori:Liguori, Francesca; Barbaro, Pierluigi; Said, Bilel; Galarneau, Anne; Dal santo, Vladimiro; Passaglia, Elisa; Feis, Alessandro/titolo:Unconventional Pd@sulfonated silica monoliths catalysts for selective partial hydrogenation reactions under continuous flow/doi:10.1002%2Fcctc.201700381/rivista:ChemCatChem (Print)/anno:2017/pagina_da:3245/pagina_a:3258/intervallo_pagine:3245–3258/volume

Doubly functionalized, hierarchical-porosity silica monoliths were synthesized by postgrafting of sulfonic groups and in situ growth of Pd nanoparticles in that order. PdNP of 3.1 nm size located in the mesopores of the material showed to be evenly d

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b2f351efa209ad7eb9932d5a74c4cfc4
https://doi.org/10.1002/cctc.201700381