Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Phillip Biallas"'
Publikováno v:
Organic letters. 24(10)
An iridium-catalyzed, reductive alkylation of abundant tertiary lactams and amides using 1-2 mol % of Vaska's complex (IrCl(CO)(PPh3)2), tetramethyldisiloxane (TMDS), and difluoro-Reformatsky reagents (BrZnCF2R) for the general synthesis of medicinal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6623257aa5676c6303d9575701253502
https://pubmed.ncbi.nlm.nih.gov/35258311
https://pubmed.ncbi.nlm.nih.gov/35258311
Publikováno v:
European Journal of Organic Chemistry. 2020:4389-4398
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fdbce3ccfa6d7ae5b9f25ffc38b6b5b5
https://doi.org/10.1002/ejoc.202000641
https://doi.org/10.1002/ejoc.202000641
Publikováno v:
The Journal of Organic Chemistry. 84:1654-1663
Diazidated malonamides derived from amines and diazidated diethyl malonate react with lithiated alcohols through nucleophilic substitution reactions where azide acts as an unconventional leaving group. This deazidoalkoxylation leads to the formal con
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::687b69554af30348dc0a3575a168d864
https://doi.org/10.1021/acs.joc.8b02969
https://doi.org/10.1021/acs.joc.8b02969
Publikováno v:
Polymer Chemistry. 10:60-64
A diazidated malonate derivative was employed as a monomer for the reagent-free one-pot synthesis of several polyamides containing geminal diazido moieties within the polymer backbone. Using different diamines, azide-rich polyamides with diverse prop
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2eead2b6d49b5e6bcd19f52652c32d52
https://doi.org/10.1039/c8py01087k
https://doi.org/10.1039/c8py01087k
Publikováno v:
European Journal of Organic Chemistry. 2017:1526-1539
We have discovered that 2,2-diazido acylacetates, a class of compounds with essentially unknown reactivity, can be coupled to amines through a new strategy that does not involve any reagents. 2,2-Diazido acetate is the unconventional leaving group un
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b560e30d061b020406ab272cec720d88
https://doi.org/10.1002/ejoc.201601625
https://doi.org/10.1002/ejoc.201601625
Autor:
Phillip Biallas, Stefan F. Kirsch
Publikováno v:
Tetrahedron Letters. 58:4209-4211
The complete hydrogenolysis of compounds containing the geminal diazido functionality is described. Using hydrogen over palladium on charcoal, the diazides are reduced, and primary amines are obtained. For example, aminomalonates and glycines are gen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::03228d535c7154206e744ddb21a12384
https://doi.org/10.1016/j.tetlet.2017.09.066
https://doi.org/10.1016/j.tetlet.2017.09.066
Publikováno v:
Organicbiomolecular chemistry. 15(15)
A mild and convenient protocol for the oxidative cleavage of 1,3-diketone compounds is described. Under metal-free conditions, the method converts the 1,3-dicarbonyls into amides when treated with (nBu4N)N3 and iodine in the presence of an amine at r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d73b7a0110d786d46ee38ba1ff50f5e8
https://pubmed.ncbi.nlm.nih.gov/28362452
https://pubmed.ncbi.nlm.nih.gov/28362452
Autor:
Andreas P. Haering, Phillip Biallas, Stefan F. Kirsch, Markus Roggel, My Linh Tong, Martin Juebermann, Fabian Mohr, Hellmuth Erhardt, Andreas Kotthaus
Publikováno v:
ChemInform. 47
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cb18654bda9505eb93dd762b9f76c732
https://doi.org/10.1002/chin.201618069
https://doi.org/10.1002/chin.201618069
Autor:
Fabian Mohr, My Linh Tong, Phillip Biallas, Martin Jübermann, Stefan F. Kirsch, Andreas Kotthaus, Andreas P. Häring, Hellmuth Erhardt, Markus Roggel
Publikováno v:
The Journal of organic chemistry. 80(24)
Geminal diazides constitute a rare class of compounds where only a limited number of methods are available for their synthesis. We present the reaction of 1,3-dicarbonyl compounds (as exemplified by malonates, 3-oxoesters, and 1,3-diketones) with mol
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::707c8ae9ddc4f451dc46ab9d08b88578
https://pubmed.ncbi.nlm.nih.gov/26623662
https://pubmed.ncbi.nlm.nih.gov/26623662
Autor:
'Phillip Biallas
Publikováno v:
Ken Yamazaki
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=r3c4b2081b22::121015bf0b33e30a7bc93991929d1d14