Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Philipp Roesle"'
Publikováno v:
ACS Catalysis. 5:5951-5972
Isomerizing functionalization reactions that convert the internal double bonds of unsaturated fatty acids from plant or algae oils to a terminal functional group are attractive because they can generate linear long-chain α,ω-difunctional compounds
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d6f9dc18fec7566439a2f43dca23407e
https://doi.org/10.1021/acscatal.5b01508
https://doi.org/10.1021/acscatal.5b01508
Publikováno v:
ACS Catalysis. 5:4519-4529
α,ω-Difunctionalized long-chain compounds A-(CH2)n-B are valuable intermediates and monomers. Unsymmetrical compounds with two different functional groups (A ≠ B) are, however, only accessible by multistep traditional organic syntheses to date. W
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::32d930d600f09ae558da9f1c079e53fb
https://doi.org/10.1021/acscatal.5b00825
https://doi.org/10.1021/acscatal.5b00825
Autor:
Philipp Roesle, Philipp Wucher, Laura Falivene, Zhongbao Jian, Lucia Caporaso, Inigo Göttker-Schnetmann, Stefan Mecking, Luigi Cavallo
Publikováno v:
Chemistry - A European Journal. 21:2062-2075
Two series of cationic palladium(II) methyl complexes {[(2-MeOC6H4)2PC6H4SO2NHC6H3(2,6-R1,R2)]PdMe}2[A]2 (X1+-A: R1=R2=H: H1+-A; R1=R2=CH(CH3)2: DIPP1+-A; R1=H, R2=CF3: CF31+-A; A=BF4 or SbF6) and neutral palladium(II) methyl complexes {[(2-MeOC6H4)2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d8f8594644c481ab81faebc084a61b6a
https://doi.org/10.1002/chem.201404856
https://doi.org/10.1002/chem.201404856
Autor:
Stefan Mecking, Philipp Roesle, Peter G. Kroth, Carolina Río Bártulos, Julia Zimmerer, Sandra K. Hess, Bernard Lepetit, Angelika Eckert, Florian Stempfle
Publikováno v:
Angewandte Chemie. 126:6918-6922
Current efforts to technically use microalgae focus on the generation of fuels with a molecular structure identical to crude oil based products. Here we suggest a different approach for the utilization of algae by translating the unique molecular str
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::04b5c4767837e1baccb2e506a79424b2
https://doi.org/10.1002/ange.201403991
https://doi.org/10.1002/ange.201403991
Autor:
Philipp Roesle, Luigi Cavallo, Inigo Göttker-Schnetmann, Francesco Ragone, Lucia Caporaso, Stefan Mecking, Philipp Wucher
Publikováno v:
Proceedings of the National Academy of Sciences. 108:8955-8959
In modern methods for the preparation of small molecules and polymers, the insertion of substrate carbon–carbon double bonds into metal–carbon bonds is a fundamental step of paramount importance. This issue is illustrated by Mizoroki–Heck coupl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aa541ebd8301cd63b10fe88f89247170
https://doi.org/10.1073/pnas.1101497108
https://doi.org/10.1073/pnas.1101497108
Autor:
Philipp Roesle, Verena Goldbach, Luigi Cavallo, Manuel Schnitte, Stefan Mecking, Lucia Caporaso
Publikováno v:
Journal of the American Chemical Society. 136(48)
Theoretical studies on the overall catalytic cycle of isomerizing alkoxycarbonylation reveal the steric congestion around the diphosphine coordinated Pd-center as decisive for selectivity and productivity. The energy profile of isomerization is flat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::94d1475b20fcb607e566d579309f7e28
https://pubmed.ncbi.nlm.nih.gov/25415929
https://pubmed.ncbi.nlm.nih.gov/25415929
Autor:
Florian Stempfle, Gerhard Müller, Lucia Caporaso, Stefan Mecking, Josefine T. Christl, Luigi Cavallo, Philipp Roesle
Publikováno v:
ChemSusChem. 7(12)
The 1,2-(CH2P(1-adamantyl)2)2C6H4 (dadpx) coordinated palladium complex [(dadpx)Pd(OTf)2] (1) is a catalyst precursor for the isomerizing methoxycarbonylation of the internal double bond of methyl oleate, with an unprecedented selectivity (96 %) for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::758e7be59acbf50b4890c25bab20859d
https://pubmed.ncbi.nlm.nih.gov/25314333
https://pubmed.ncbi.nlm.nih.gov/25314333
Autor:
Gregor Voit, Alexandra Tchernook, Inigo Göttker-Schnetmann, Thomas Wiedemann, Philipp Roesle, Stefan Mecking
Publikováno v:
Journal of the American Chemical Society. 136(5)
The neutral κ(2)N,O-salicylaldiminato Ni(II) complexes [κ(2)N,O-{(2,6-(3',5'-R2C6H3)2C6H3-N═C(H)-(3,5-I2-2-O-C6H2)}]NiCH3(pyridine)] (1a-pyr, R = Me; 1b-pyr, R = Et; 1c-pyr, R = iPr) convert ethylene to hyperbranched low-molecular-weight oligomer
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::571e12ebb34d5c1933f662edcf49acaf
https://pubmed.ncbi.nlm.nih.gov/24450458
https://pubmed.ncbi.nlm.nih.gov/24450458
Autor:
Patrick B. Smith, Richard A. Gross, E. de Jong, M. A. Dam, L. Sipos, G.-J. M. Gruter, B. Kollbe Ahn, Stefan Kraft, X. Susan Sun, Hongzhi Liu, Jinwen Zhang, H. N. Cheng, Michael K. Dowd, Atanu Biswas, Taizo Kabe, Takeharu Tsuge, Takaaki Hikima, Masaki Takata, Akio Takemura, Tadahisa Iwata, Wenhua Lu, Jon E. Ness, Wenchun Xie, Xiaoyan Zhang, Fei Liu, Jiali Cai, Jeremy Minshull, Yuya Tachibana, Takashi Masuda, Masahiro Funabashi, Ken-ichi Kasuya, Masao Kunioka, Yu-Rong Zhang, Yi-Xin Yang, Jia-Li Cai, Wen-Hua Lv, Wen-Chun Xie, Yu-Zhong Wang, Chen Liu, Timothy E. Long, S. Richard Turner, Alan Lyons, Florian Stempfle, Philipp Roesle, Stefan Mecking, Timothy W. Abraham, Seema Agarwal, Qiao Jin, Samarendra Maji, John Masani Nduko, Ken’ichiro Matsumoto, Seiichi Taguchi, Jun-ichi Kadokawa, J.-M. Raquez, A.-L. Goffin, E. Duquesne, Y. Habibi, A. Dufresne, Ph. Dubois, Gerard Lligadas, Juan C. Ronda, Marina Galià, Virginia Cádiz, Bart A. J. Noordover, Lidia Jasinska-Walc, Inge van der Meulen, Robbert Duchateau, Cor E. Koning, C. M. Chaleat, M. Nikolic, R. W. Truss, I
Autor:
Luigi Cavallo, Heiko M. Möller, Philipp Roesle, Lucia Caporaso, Christoph J. Dürr, Stefan Mecking
The weakly coordinated triflate complex [(P^P)Pd(OTf)](+)(OTf)(-) (1) (P^P = 1,3-bis(di-tert-butylphosphino)propane) is a suitable reactive precursor for mechanistic studies of the isomerizing alkoxcarbonylation of methyl oleate. Addition of CH(3)OH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b0d0d6c3eba49541b21bba2df9ac957a
http://hdl.handle.net/11386/3879848
http://hdl.handle.net/11386/3879848