Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Philipp Constantinidis"'
Autor:
Florian Hirsch, Patrick Hemberger, Sjors Bakels, Ingo Fischer, Anouk M. Rijs, Engelbert Reusch, Philipp Constantinidis
Publikováno v:
The Journal of Physical Chemistry A, 122, 49, pp. 9563-9571
The Journal of Physical Chemistry A, 122, 9563-9571
The Journal of Physical Chemistry A, 122, 9563-9571
Ortho-benzyne, a Kekule-type biradical is considered to be a key intermediate in the formation of polycyclic aromatic hydrocarbons (PAH) and soot. In the present work we study the ortho-benzyne self-reactions in a hot micro-reactor and identify the h
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::71972aed879c1f19193a8c526c78f0e7
https://hdl.handle.net/2066/199557
https://hdl.handle.net/2066/199557
Publikováno v:
Angewandte Chemie. 129:8113-8116
Stickstoff-haltige resonanzstabilisierte Radikale wie Picolyl spielen eine wichtige Rolle in Verbrennungsprozessen und in der Astrochemie. Sie wurden jedoch bislang kaum untersucht, da es schwierig ist, sie isomerenselektiv zu erzeugen. Schwellenphot
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::423103e4882734dba41c76172774ad0b
https://doi.org/10.1002/ange.201703433
https://doi.org/10.1002/ange.201703433
Publikováno v:
Angewandte Chemie International Edition. 56:8000-8003
Nitrogen-containing resonance-stabilized radicals like picolyl are important in combustion chemistry and astrochemistry. They have only been scarcely studied, because an isomer-selective generation is often difficult. Here we present threshold photoe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a8e4af3aef480bc83b3cc43908ff57ed
https://doi.org/10.1002/anie.201703433
https://doi.org/10.1002/anie.201703433
Autor:
Stefan Ullrich, Holger Braunschweig, Alfredo Vargas, William C. Ewing, Christoph Schneider, Ingo Fischer, Philipp Constantinidis, Fergus R. Knight, Theresa Dellermann, Merlin Hess, J. Derek Woollins, Anna Rempel
Publikováno v:
Angewandte Chemie. 128:5697-5700
Die Reaktionen eines Diborens mit elementaren Selen oder Tellur fuhren zur Bildung eines Diboraselenirans bzw. eines Diboratellurirans. Diese Reaktionen erinnern an die Bindung von niedervalentem Sauerstoff und Stickstoff bei der Bildung von Oxiranen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ebfb3cd3075f489571668aa34f2f23a1
https://doi.org/10.1002/ange.201601691
https://doi.org/10.1002/ange.201601691
Publikováno v:
Chemistry : a European Journal, 24, 7647-7652
Chemistry : a European Journal, 24, 30, pp. 7647-7652
Chemistry : a European Journal, 24, 30, pp. 7647-7652
We investigate the self-reaction of benzyl, C7 H7 , in a high-temperature pyrolysis reactor. The work is motivated by the observation that resonance-stabilized benzyl radicals can accumulate in reactive environments and contribute to the formation of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d8189a7bb65ad3ea2b09d28e223a10d
http://hdl.handle.net/2066/192134
http://hdl.handle.net/2066/192134
Autor:
Rüdiger Bertermann, Jan Mies, Alfredo Vargas, Thomas Kramer, Ashwini K. Phukan, Holger Braunschweig, Rian D. Dewhurst, Philipp Constantinidis, William C. Ewing, Theresa Dellermann, Ingo Fischer
Publikováno v:
Angewandte Chemie. 127:13282-13286
Kation-π-Wechselwirkungen sind eine der wichtigsten Klassen von nichtkovalenten Bindungen. Sie konnen in der Biologie, Chemie und den Materialwissenschaften beobachtet werden. Jedoch spielen diese bisher nur in Verbindung mit sehr starken kovalenten
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e4db33d2be7cb6beb0fc6baeb4fc3f60
https://doi.org/10.1002/ange.201506487
https://doi.org/10.1002/ange.201506487
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 641:362-368
Seven lanthanide containing strand-like coordination polymers and dimeric complexes were obtained in a reversible reaction from 1, 3-thiazole (thz) and LnCl3 (Ln = La, Ce, Pr, Nd). The reactions do not require activation and render coordination polym
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3d0a091318f7dbcd9c4c7d62ac0466ed
https://doi.org/10.1002/zaac.201400521
https://doi.org/10.1002/zaac.201400521
Autor:
R. Wirthensohn, Ingo Fischer, Hans-Christian Schmitt, Klaus Müller-Buschbaum, Fabian Schönfeld, Philipp Constantinidis
Publikováno v:
Dalton Trans.. 43:15398-15406
An attempt to control the three structural features linkage, structural dimensionality and coordination mode is presented for the combination of Fe(II) and Fe(III) chlorides together with the ditopic ligand piperazine (pipz). Thermal conversion of sm
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0acf0b4c07085134f052f68f3e5ef5f5
https://doi.org/10.1039/c4dt01987c
https://doi.org/10.1039/c4dt01987c
Autor:
Ingo Fischer, Anke Krueger, Philipp Constantinidis, Melanie Lang, Johannes Auerswald, Jörg Herterich
Publikováno v:
The Journal of Physical Chemistry A. 118:2915-2921
Recently 1-(phenylethynyl)naphthalene (1-PEN) was suggested to be the primary dimerization product of phenylpropargyl radicals and therefore an important polycyclic hydrocarbon in combustion processes. Here we describe a spectroscopic investigation o
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0b627beb2c0f94c46e1212b8e6ad4f81
https://doi.org/10.1021/jp412482p
https://doi.org/10.1021/jp412482p
Publikováno v:
The Journal of Physical Chemistry A, 121, 181-191
The Journal of Physical Chemistry A, 121, 1, pp. 181-191
The Journal of Physical Chemistry A, 121, 1, pp. 181-191
The propargyl radical is considered to be of key importance in the formation of the first aromatic ring in combustion processes. Here we study the bimolecular (self-) reactions of propargyl in a high-temperature pyrolysis flow reactor. The aromatic r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b27ba2e640ec49ee1843d435d09c8332
https://pubmed.ncbi.nlm.nih.gov/27997191
https://pubmed.ncbi.nlm.nih.gov/27997191