Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Philip P. Duce"'
Autor:
John Ibechem, Pilar Guardado, Colin D. Hubbard, John Burgess, Diane L. Elvidge, Philip P. Duce, Michael J. Blandamer
Publikováno v:
J. Chem. Soc., Faraday Trans.. 88:215-222
The dependence of rate constants for base hydrolysis on solvent composition for several iron(II)–diimine complexes has been established for aqueous ethane-1,2-diol (ethylene glycol) and aqueous propane-1,2,3-triol (glycerol) mixtures, and for aqueo
Publikováno v:
Transition Metal Chemistry. 8:308-312
Rate constants are reported for the reaction ofcis-Pt(4-CNpy)2Cl2 with thiourea in aqueous solutions of potassium chloride, gadolinium chloride, and tetraethylammonium chloride. From these kinetic results and measurements of solubilities of the two r
Autor:
Philip P. Duce, Martyn V. Twigg, John Burgess, Keith S. Payne, Paul Wellings, Robert Sherry, Michael J. Blandamer
Publikováno v:
Transition Metal Chemistry. 9:163-173
Kinetics of nucleophilic substitution at a range of low-spin iron(II)diimine complexes have been examined in the presence of a variety of salts, to probe the role of hydroxide and cyanide as nucleophiles and of other ions in ion association equilibri
Autor:
John Burgess, Gareth J. Baker, A. Olabode Adeniran, Gabriel J. Bennett, Michael J. Blandamer, Nilam K. Dhammi, Philip P. Duce
Publikováno v:
Transition Metal Chemistry. 7:183-187
Rate constants are reported for mercury(II)-catalysed aquation of thetrans-[Rh(en)2Cl2]+, [Cr(NH3)5Cl]2+, andcis-[Cr(NH3)4(OH2)Cl]2+ cations in water and in methanol-, ethanol-, and acetonitrile-water solvent mixtures. In the case oftrans-[Rh(en)2Cl2
Autor:
Michael R. Abraham, Philip P. Duce, Priscilla L. Grellier, David V. Prior, Jeffrey J. Morris, Peter J. Taylor
Publikováno v:
Tetrahedron Letters. 29:1587-1590
Publikováno v:
Journal of Inorganic and Nuclear Chemistry. 43:3103-3106
Solubilities and enthalpies of solution are reported for trimethylamine sulphur trioxide, Me3NSO3, dissolving in water and in aqueous potassium bromide and aqueous tetra-n-butylammonium bromide solutions. From these solubility data and published kine
Publikováno v:
Transition Metal Chemistry. 7:10-13
Rate constants are reported for 12-tungstocobaltate(III) [CoW12O40]5− oxidation of iodide in water and in binary aqueous solvent mixtures containing up to 40% methanol, 40% acetonitrile, or 60% dimethyl sulphoxide. From these kinetic results, solub
Autor:
John Burgess, Nrinder Gosal, Pilar Guardado, Philip P. Duce, Michael J. Blandamer, Robert Sherry, Francisco Sánchez
Publikováno v:
Transition Metal Chemistry. 9:3-8
Enthalpies of solution (298 K) are reported for NiCl2 · 6H2O, CoCl2 · 6H2O, and FeCl2 · 4H2O in aqueous methanol (0–40% methanol) and for NiCl2 · 6H2O, 2,2′-bipyridyl, and water in aqueous dimethyl sulphoxide (0–60% DMSO). Solubilities (298
Autor:
Damien M. Sweeney, Timothy Digman, John Burgess, Raymond H. Reynolds, John P. McCann, Michael J. Blandamer, Philip P. Duce
Publikováno v:
Transition Metal Chemistry. 8:148-152
Activation enthalpies have been determined for aquation of thetris(1,10-phenanthroline)iron(II) cation and for its reaction with hydroxide in 20, 40, and 80% (by volume) methanol, and for its reaction with cyanide in 20 and 40% methanol. Enthalpies o
Publikováno v:
Transition Metal Chemistry. 6:368-371
Rate constants have been determined for the reaction of [PtCl4]2− with cyanide in water and in 20% and 40% (v/v) methanol, and for the reaction of [Pd(Et4dien)Cl]+ with thiourea in water, in 50% methanol, and in 50% DMSO, in all cases at 298.2K. Th