Zobrazeno 1 - 10
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pro vyhledávání: '"Philip Mountford"'
Autor:
Philip Mountford
Publikováno v:
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9712d5f1c730ef6f10a8125b3f174139
https://doi.org/10.1016/b978-0-12-820206-7.00039-1
https://doi.org/10.1016/b978-0-12-820206-7.00039-1
Autor:
Philip Mountford, Benjamin A. Clough
Publikováno v:
Organometallics. 37:3558-3572
We report a combined synthetic, mechanistic, and computational (DFT) study of the synthesis of new diamide-amine-supported titanium borylimides and their reactions with TolCCH and ArFCCH (Tol = 4-C6H4Me, ArF = C6F5). Reaction of Ti{NB(NAr′CH)2}Cl2(
Autor:
Mariana, Luna Barros, Michael G, Cushion, Andrew D, Schwarz, Zoë R, Turner, Philip, Mountford
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 48(13)
A new family of sterically demanding N2N' heteroscorpionate pro-ligands (HC(tBu2pz)2SiMe2N(H)R (R = iPr, tBu, Ph, Xyl)) has been prepared via a straightforward modular synthetic route. An extensive study into the synthesis and characterisation of lit
Autor:
Benjamin A, Clough, Simona, Mellino, Andrey V, Protchenko, Martin, Slusarczyk, Laura C, Stevenson, Matthew P, Blake, Bowen, Xie, Eric, Clot, Philip, Mountford
Publikováno v:
Inorganic chemistry. 56(17)
We report a combined experimental and computational study of the synthesis and electronic structure of titanium borylimido compounds. Three new synthetic routes to this hitherto almost unknown class of Group 4 imide are presented. The double-deproton
Autor:
Dragoslav Vidovic, Philip Mountford, Matthew P. Blake, Simon Aldridge, Cameron Jones, Joseph A. B. Abdalla, Jesús Campos, Andrew D. Schwarz, Juan Urbano, Andrey V. Protchenko
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Reduction of indium boryl precursors to give two- and three-dimensional M−M bonded networks is influenced by the choice of supporting ligand. While the unprecedented nanoscale cluster [In(boryl)] (with an In@In@In(boryl) concentric structure), can
Publikováno v:
Journal of the American Chemical Society. 139(32)
We report a combined synthetic, mechanistic, and theoretical study of the first borylimido complex of a rare earth metal, (NacNac
Autor:
Adam F. Russell, Richard T. Scott, Gerard H. J. van Doremaele, Alexandra Berthoud, Richard A. Collins, Philip Mountford, Raffaele Bernardo
Publikováno v:
Organometallics. 36(11)
A series of cyclopentadienyl-κ1-amidinate titanium complexes Cp*Ti{NC(ArR)NiPr2}Me2 (ArR = 4-C6H4R, where R = H (1-Me), CF3 (5-Me), tBu (6-Me), or NMe2 (7-Me)) with different para-substituents in the amidinate ligand were synthesized and structurall
Publikováno v:
Macroheterocycles. 10(1)
Square-planar diamagnetic nickel(II) complexes 5a and 5b containing 16-membered diamino-diimino ligands were prepared from the corresponding open-chain complexes 2a and 2b via condensation with o-phthalic dialdehyde in methanol. The solid-state struc
Autor:
Simon Aldridge, Andrew D. Schwarz, Philip Mountford, Andrey V. Protchenko, Deepak Dange, Cameron Jones, Matthew P. Blake
Publikováno v:
Journal of the American Chemical Society. 136:10902-10905
Monomeric five-valence-electron bis(boryl) complexes of gallium, indium, and thallium undergo oxidative M–C bond formation with 2,3-dimethylbutadiene, in a manner consistent with both the redox properties expected for MII species and with metal-cen
Autor:
Nicholas Phillips, Michael J. Kelly, Simon Aldridge, Cameron Jones, Krishna Hassomal Birjkumar, Jeffrey Harmer, Deepak Dange, Andrew D. Schwarz, Christina Y. Tang, Nikolas Kaltsoyannis, Philip Mountford, Rémi Tirfoin, Andrey V. Protchenko
Publikováno v:
Nature Chemistry. 6:315-319
The chemistry of the Group 13 metals is dominated by the +1 and +3 oxidation states, and simple monomeric M(II) species are typically short-lived, highly reactive species. Here we report the first thermally robust monomeric MX2 radicals of gallium, i