Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Philip J. W. Elder"'
Autor:
Peter C. Ho, Patrick Szydlowski, Jocelyn Sinclair, Philip J. W. Elder, Joachim Kübel, Chris Gendy, Lucia Myongwon Lee, Hilary Jenkins, James F. Britten, Derek R. Morim, Ignacio Vargas-Baca
Publikováno v:
Nature Communications, Vol 7, Iss 1, Pp 1-10 (2016)
Similarly to halogen bonding, the heavier chalcogens are capable of forming supramolecular links with electron rich sites. Here, the authors show that these forces can allow the formation of well-defined cyclic structures that are stable in solution
Externí odkaz:
https://doaj.org/article/cf1ebf0553e54ae4936f6e679632a9a1
Publikováno v:
Physical Chemistry Chemical Physics. 18:30740-30747
The frequency of the resonance of 125Te of two organo-ditellurides, R–Te–Te–R (R = 4-CH3C6H4 and 2-(CH3)2NCH2C6H4), in solution undergoes a low-field shift as the concentration of the sample increases. In sharp contrast, the resonance of a ster
Autor:
Tobias A. Engesser, René T. Boeré, Mona Taghavikish, Ingo Krossing, Harald Scherer, Tracey L. Roemmele, Tristram Chivers, Philip J. W. Elder
Publikováno v:
Heteroatom Chemistry. 25:501-513
Density functional theory (DFT) calculations for the six-membered ring 1,4-(CH2)2(PtBu)4 (1), the dimer (PtBu2)2 (2) and the 2,5-chalcogenated derivatives of 1, 3a (E = S) and 3b (E = Se), and the corresponding cation radicals and dications predict s
Publikováno v:
European Journal of Inorganic Chemistry. 2013:2867-2876
The reaction of H2C(PCl2)2 with four equivalents of iPrMgCl produces H2C(PiPr2)2, which was treated with tellurium in boiling toluene, or selenium in toluene at room temperature, to give the monochalcogenides EPiPr2CH2PiPr2 (E = Te, 4a; E = Se, 4b) i
Autor:
Ignacio Vargas-Baca, Jeff C. Landry, Anthony F. Cozzolino, Philip J. W. Elder, Allison E.A. Chapman
Publikováno v:
Journal of Organometallic Chemistry. 716:11-18
Treatment of N,N-dialkyl-4-[4-nitrophenyl)diazenyl] anilines with a mercury(II) salt in anhydrous trifluoroacetic acid results in single and double metallation of the ring with less electron density. The seemingly counterintuitive outcome of the reac
Publikováno v:
Coordination Chemistry Reviews. 255:1426-1438
The crystal structures of tellurium compounds frequently display intermolecular contacts between the chalcogen and atoms possessing lone pairs of electrons. Analysis of the data deposited in the Cambridge crystallographic database shows that the shor
Publikováno v:
Main Group Chemistry. 9:117-133
Publikováno v:
Canadian Journal of Chemistry. 87:1055-1062
Acetylferrocene readily forms an adduct with BF3. The product is a neutral model for protonated acetylferrocene, a species that is a crucial intermediate in the formation of 1,3,5-trisferrocenyl-benzene and other conjugated heterometallic derivatives
Autor:
Hilary A. Jenkins, Joachim Kübel, Philip J. W. Elder, James F. Britten, Peter C. Ho, Chris Gendy, Jocelyn Sinclair, Derek R. Morim, Lucia Myongwon Lee, Ignacio Vargas-Baca, Patrick Szydlowski
Publikováno v:
Nature Communications
Nature Communications, Vol 7, Iss 1, Pp 1-10 (2016)
Nature Communications, Vol 7, Iss 1, Pp 1-10 (2016)
Organic molecules with heavy main-group elements frequently form supramolecular links to electron-rich centres. One particular case of such interactions is halogen bonding. Most studies of this phenomenon have been concerned with either dimers or inf
Autor:
Tristram Chivers, Philip J. W. Elder
Publikováno v:
ChemInform. 44
The trisulfur radical anion [S3]˙− is well-known from inorganic chemistry textbooks as the blue chromophore in ultramarine blues in which this highly reactive species is trapped in a zeolitic framework. Recent findings have revealed that [S3]˙−