Zobrazeno 1 - 10
of 177
pro vyhledávání: '"Philip E. Eaton"'
Autor:
Tyler Fahrenhorst-Jones, David L. Marshall, Jed. M. Burns, Gregory K. Pierens, Robert E. Hormann, Allison M. Fisher, Paul V. Bernhardt, Stephen J. Blanksby, G. Paul Savage, Philip E. Eaton, Craig M. Williams
Publikováno v:
Chemical Science. 14:2821-2825
1-Azahomocubane has been prepared 56 years after the parent hydrocarbon. Introduction of a nitrogen atom into this constrained polycyclic environment resulted in minimal changes to the framework geometry, with s-character of the nitrogen lone pair in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ca5fc35dd6725ef4ebb7fbf3ef4c62ec
https://doi.org/10.1039/d3sc00001j
https://doi.org/10.1039/d3sc00001j
Publikováno v:
European Journal of Organic Chemistry. 2017:2627-2630
The carbon–carbon bonding in cubane is shown not to be along the C–C vectors between carbon atoms at the corners of a cube. Instead, the bonding is “bent” as seen in a new single-crystal X-ray structure of cubane at 93 K. The bent bond angles
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9bdcdfb23af4976eac69b201fea663d3
https://doi.org/10.1002/ejoc.201700427
https://doi.org/10.1002/ejoc.201700427
Publikováno v:
Propellants, Explosives, Pyrotechnics. 27:1-6
Octanitrocubane, the first new nitrocarbon in 18 years, is introduced as a potential explosive of great power. Its synthesis and characterization are described.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0112b5e28cc8834aab4a888549cf5d62
https://doi.org/10.1002/1521-4087(200203)27:1<1::aid-prep1>3.0.co
https://doi.org/10.1002/1521-4087(200203)27:1<1::aid-prep1>3.0.co
Publikováno v:
Journal of the American Chemical Society. 123:1289-1293
Ab initio molecular orbital and density functional calculations on isodesmic disproportionation reactions of nitrated cubanes indicate that the repulsion between nitro groups on adjacent carbons in octanitrocubane (ONC) is surprisingly small and that
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b1c7b7718a7cea4248e1d06a437445f6
https://doi.org/10.1021/ja001636t
https://doi.org/10.1021/ja001636t
Publikováno v:
Advanced Materials. 12:1143-1148
More powerful and less shock-sensitive explosives are continually being sought for both military and commercial use. Here the qualities a potential candidate must possess to make a good explosive are detailed, and the synthesis of octanitrocubane—a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::138b72e308bb36ec54f5c7bdc187a8b7
https://doi.org/10.1002/1521-4095(200008)12:15<1143::aid-adma1143>3.0.co
https://doi.org/10.1002/1521-4095(200008)12:15<1143::aid-adma1143>3.0.co
Publikováno v:
Angewandte Chemie International Edition. 39:401-404
Four of the eight nitro groups of octanitrocubane 1 are introduced by functional group modification, three more by the astonishingly rapid, low-temperature N2O4 nitration of sequentially formed polynitrocubyl anions, and the eighth and last by nitros
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0488f84bc75f09929082da7c56106676
https://doi.org/10.1002/(sici)1521-3773(20000117)39:2<401::aid-anie401>3.0.co
https://doi.org/10.1002/(sici)1521-3773(20000117)39:2<401::aid-anie401>3.0.co
Publikováno v:
Angewandte Chemie. 112:422-426
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ff6134f674305fc2b479245e462cb918
https://doi.org/10.1002/(sici)1521-3757(20000117)112:2<422::aid-ange422>3.0.co
https://doi.org/10.1002/(sici)1521-3757(20000117)112:2<422::aid-ange422>3.0.co
Publikováno v:
Journal of the American Chemical Society. 121:4111-4123
On treatment with an organolithium 1,4-diiodocubane generates cubane-1,4-diyl, a highly reactive species, shown here to be a versatile precursor to numerous aryl substituted cubanes, available now for the first time in high yield. The diyl is demonst
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d6948a0924ec2818bb33a45101f636bc
https://doi.org/10.1021/ja983441f
https://doi.org/10.1021/ja983441f
Autor:
Eric Punzalan, Jianchang Li, Philip E. Eaton, Jürgen Hain, Kirill Lukin, Richard Gilardi, Nobuhiro Kanomata
Publikováno v:
Journal of the American Chemical Society. 119:9591-9602
Nitro groups on alternate corners of cubane enhance the acidity of cubyl hydrogen (pKa ∼21) and provide sufficient activation for ready anion formation. The sodium salt of 1,3,5,7-tetranitrocubane reacts easily with electrophiles and leads thereby
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5d7fc625fe853267773a8bf78c0dd0f2
https://doi.org/10.1021/ja970552q
https://doi.org/10.1021/ja970552q
Publikováno v:
Journal of Medicinal Chemistry. 40:1165-1168
Cubylcarbinylamine (1a), (4-cyclopropylcubyl)carbinylamine (1b), and (4-phenylcubyl)carbinylamine (1c) were synthesized and shown to be time-dependent, irreversible inactivators of monoamine oxidase B (MAO B). Substrate protects the enzyme from inact
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::63e68c55d0c368c3682d15c216469e69
https://doi.org/10.1021/jm9606249
https://doi.org/10.1021/jm9606249