Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Philip Dimitrov"'
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 55:3697-3704
Fast polymerization of isobutylene (IB) initiated by tert-butyl chloride using ethylaluminum dichloride·bis(2-chloroethyl) ether complex (T. Rajasekhar, J. Emert, R. Faust, Polym. Chem. 2017, 8, 2852) was drastically slowed down in the presence of i
Publikováno v:
Macromolecules. 45:8598-8603
The carbocationic polymerization of isobutylene (IB), co-initiated by GaCl3 or FeCl3·dialkyl ether 1:1 complexes has been investigated in hexanes in the −20 to 10 °C temperature range. In contrast to AlCl3·diisopropyl ether (AlCl3·i-Pr2O) compl
Publikováno v:
Macromolecules. 45:3318-3325
The carbocationic polymerization of isobutylene (IB), co-initiated by AlCl3/ether complexes, has been reexamined and extended to different dialkyl ethers. In the absence of a proton trap, 2,6-di-tert-butylpyridine (DTBP), the polymerization of IB by
Autor:
Barbara Gajewska, Natalia Toncheva-Moncheva, Stanislav Rangelov, Christo B. Tsvetanov, Peter F. W. Simon, Philip Dimitrov
Publikováno v:
Polymer Bulletin. 68:2175-2185
The formation of well-defined colloidal particles (mesoglobules) from the thermosensitive polymer poly(methoxydiethyleneglycol methacrylate) was observed in dilute aqueous solutions (0.5–1.0 g/L) by turbidimetry and dynamic light scattering (DLS).
Publikováno v:
Macromolecules. 44:1831-1840
The complex mechanism of the carbocationic rearrangements leading to a variety of olefin (exo-, endo-, tri-, and tetra-substituted) end groups in the cationic polymerization of isobutylene (IB) catalyzed by ethylaluminum dichloride (EtAlCl2) in nonpo
Autor:
Rudolf Faust, Philip Dimitrov
Publikováno v:
Macromolecules. 43:1724-1729
The propagation rate constant, kp, for the cationic polymerization of α-methylstyrene (αMeSt) was determined. First, the polymerization of αMeSt was carried out initiated by the diαMeStHCl/SnBr4 initiator/coinitiator system in dichloromethane (DC
Autor:
Philip Dimitrov
Publikováno v:
Demokratizatsiya: The Journal of Post-Soviet Democratization. 17:310-323
There are authors who claim that a populist revolution has already started in the new democracies of Europe--countries that, after the fall of the Berlin Wall, aspired to join or joined NATO or the European Union). (1) If that is the case, the implic
Publikováno v:
Macromolecules. 42:6873-6877
Well-defined high molecular weight (MW) (Mn ∼ 500 000, Mw/Mn < 1.2) dumbbell-shaped copolymers based on butyl acrylates (BA) were synthesized by atom transfer radical polymerization (ATRP) in acetone. The synthesis was carried out by polymerization
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 47:2198-2206
The anionic polymerization of butadiene initiated with 1,4-dilithio1,1,4,4-tetraphenylbutane (LiTPB) in diethyl ether (DEE) gives polybutadiene (PBD) with high 1,2 content (>70%), narrow polydispersities (1.04 < M w /M n < 1.20), and predicted molecu
Autor:
Pawel Weda, Stanislav Rangelov, Philip Dimitrov, Andrzej Dworak, Christo B. Tsvetanov, Barbara Trzebicka, Natalia Toncheva
Publikováno v:
Macromolecular Symposia. 278:89-95
Temperature responsive poly(ethoxytriethyleneglycol acrylate) (PETEGA) of Mn = 8000 and M w /M n = 2.30 was synthesized by ATRP. Dilute aqueous solutions of PETEGA exhibit lower critical solution temperature (LCST) at around 34°C. We found that PETE