Zobrazeno 1 - 10
of 58
pro vyhledávání: '"Phencyclone"'
Publikováno v:
Organic & Biomolecular Chemistry. 15:8720-8728
A series of thermally stable atropisomeric phencyclone ligands (ÎGâ¡rac > 35 kcal mol-1), bearing two chiral axes, has been successfully synthesized, taking into account the results of DFT calculations on model systems. The absolute configurat
Publikováno v:
Chemical and Pharmaceutical Bulletin. 61:1065-1070
The [4+2]π cycloadduct (3aa) of phencyclone (1a) and benzoquinone (2a) readily transformed into the corresponding [2+2]π cycloadduct (4aa) during purification. The structure of the triketo cage compound was determined by single crystal X-ray analys
Publikováno v:
Tetrahedron Letters. 54:1832-1834
With the aim of obtaining fluorogenic Diels–Alder reactions, novel phencyclone derivatives were synthesized. In a short time and under convenient reaction conditions, the formation of Diels–Alder adducts was observed by color-change and up to 33-
Autor:
Nikolay Azar, Kimberly Marshall, Olga Sklyut, Robert Rothchild, Ronald Callahan, Kerstin Rosmarion
Publikováno v:
Journal of Fluorine Chemistry. 125:1893-1907
Publikováno v:
ARKIVOC, Vol 2003, Iss 3, Pp 8-15 (2002)
When heated in the presence of atmospheric oxygen, either in diffuse room light or in the dark, phencyclone (1) undergoes autoxidation to afford 9,10-dibenzoylphenanthrene (3). The structure of 3 was elucidated via application of single crystal X-ray
Autor:
Kazunobu Harano, Masashi Eto, Yasuyuki Yoshitake, Junichi Misaka, Koji Setoguchi, Tomohiro Kawaji, Masaki Abe
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :1611-1619
A series of non-hydroxylic crystalline host compounds, [4 + 2]π cycloadducts of phencyclone and N-arylmaleimides having a bicyclo[2.2.1]heptene-7-one system, was synthesized and their inclusion behavior investigated. X-Ray crystal analyses of the in
Publikováno v:
The Chemical Educator. 6:227-234
Undergraduate organic chemistry special laboratory projects based upon the synthesis of phencyclone, 1 (a potent Diels-Alder diene), and the preparation of a series of highly hindered Diels-Alder adducts of the phencyclone, were described earlier. De
Publikováno v:
Tetrahedron Letters. 41:4395-4400
The cycloaddition of 2,5-bis(methoxycarbonyl)-3,4-diphenylcyclopentadienone with S-allyl S-methyl dithiocarbonate gave the endo cycloadduct whereas phencyclone gave a mixture of the endo and exo cycloadducts. The X-ray analysis of the cycloadduct of
Publikováno v:
Tetrahedron Letters. 39:9751-9754
A series of crystalline host compounds, which have a bicyclo[2.2.1]heptene-7-one system, has been synthesized and their inclusion behavior has been investigated. The cycloadduct of phencyclone and N-naphthylmaleimide forms a 1:1 crystalline inclusion
Publikováno v:
The Chemical Educator. 3:1-21
Synthesis of Diels—Alder adducts of phencyclone with diverse dienophiles provides the basis for a major extended module in the second-semester laboratory of an organic chemistry course. With many accessible target compounds, students can have indiv