Configurational Lability at Tetrahedral Phosphorus: syn/anti‐Isomerization of a P‐Stereogenic Phosphiranium Cation by Intramolecular Epimerization at Phosphorus.

Autor: Tipker, Ryan M., Muldoon, Jake A., Pham, Daniel H., Varga, Balazs R., Hughes, Russell P., Glueck, David S., Balaich, Gary J., Rheingold, Arnold L.

Publikováno v: Angewandte Chemie International Edition; 1/3/2022, Vol. 61 Issue 1, p1-6, 6p

Configurational Lability at Tetrahedral Phosphorus: syn/anti-Isomerization of a P-Stereogenic Phosphiranium Cation by Intramolecular Epimerization at Phosphorus.

Autor: Tipker RM; 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA., Muldoon JA; 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA., Pham DH; 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA., Varga BR; 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA., Hughes RP; 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA., Glueck DS; 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, NH, 03755, USA., Balaich GJ; Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA, 92093, USA., Rheingold AL; Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA, 92093, USA.

Publikováno v: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2022 Jan 03; Vol. 61 (1), pp. e202110753. Date of Electronic Publication: 2021 Nov 23.