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Akademický článek

Honey-like Odor Meets Single-Ion Magnet: Synthesis, Crystal Structure, and Magnetism of Cobalt(II) Complex with Aromatic Trans-Cinnamic Acid

Autor: Petr Halaš, Ivan Nemec, Radovan Herchel

Publikováno v: Magnetochemistry, Vol 9, Iss 11, p 229 (2023)

The hexacoordinate Co(II) complex [Co(neo)2(cin)][BPh4]·½Me2CO (1·½Me2CO) containing trans-cinnamic acid (Hcin) and neocuproine (neo) was prepared. The compound 1·½Me2CO was characterized via single-crystal X-ray analysis, FT-IR spectroscopy, a

Externí odkaz: https://doaj.org/article/31b62b3ef3c54597822dcc415fe68566

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Akademický článek

Anion-Dependent Synthesis of Cu(II) Complexes with 2-(1H-Tetrazol-5-yl)-1H-indole: Synthesis, X-Ray Structures, and Radical Scavenging Activity

Autor: Petr Halaš, Juraj Kuchár, Radovan Herchel

Publikováno v: Bioinorganic Chemistry and Applications, Vol 2021 (2021)

Two mononuclear Cu(II) complexes, [Cu(phen)2(HL)]ClO4·H2O·2DMF (1) and [Cu(phen)2(HL)2]·EtOH (2), comprising 1,10-phentantroline (phen) and 2-(1H-tetrazol-5-yl)-1H-indole ligand (H2L) ligands are reported. Analysis and characterization of the samp

Externí odkaz: https://doaj.org/article/34c6d69b0a324aeaaa0ed4f0a80b71ad

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Anticancer half-sandwich Ir(iii) complex and its interaction with various biomolecules and their mixtures – a case study with ascorbic acid

Autor: Lukáš Masaryk, Jakub Orvoš, Karolina Słoczyńska, Radovan Herchel, Ján Moncol, David Milde, Petr Halaš, Radka Křikavová, Paulina Koczurkiewicz-Adamczyk, Elżbieta Pękala, Róbert Fischer, Ivan Šalitroš, Ivan Nemec, Pavel Štarha

Publikováno v: Inorganic Chemistry Frontiers. 9:3758-3770

An anticancer azo bond-containing half-sandwich Ir(iii) complex oxidizes ascorbate to dehydroascorbate, and ascorbate recovers in the presence of reduced glutathione.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7d4fbc1c10448d19eb52d7ef43b4b8a1
https://doi.org/10.1039/d2qi00535b

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Stability of a half-sandwich Os(II) complex with indomethacin-functionalized ligand in the presence of carboxypeptidase A

Autor: Lukáš Masaryk, Darina Muthná, Petr Halaš, Pavel Zoufalý, Eva Peterová, Radim Havelek, Bohuslav Drahoš, David Milde, Alena Mrkvicová, Pavel Štarha

Publikováno v: Dalton transactions (Cambridge, England : 2003). 51(24)

The hydrolytically stable half-sandwich complex [Os(η6-pcym)(L2)Cl]PF6 (2) partially releases the bioactive substituent indomethacin in the presence of carboxypeptidase A.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4e90837e8335b49025d4f399ab86db5
https://pubmed.ncbi.nlm.nih.gov/35670076

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