Zobrazeno 1 - 10
of 240
pro vyhledávání: '"Peter Legzdins"'
Publikováno v:
Inorganic Chemistry. 56:11299-11309
Reaction of Cp*Mo(NO)Cl2 with 1 equiv of 1,2-bis(dimethylphosphino)ethane (dmpe) in THF at ambient temperature forms [Cp*Mo(NO)(Cl)(κ2-dmpe)]Cl (1), which is isolable as an analytically pure yellow powder in 65% yield. Further addition of 2 equiv of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::44d55b9badcb5901cd10853a5ea4f831
https://doi.org/10.1021/acs.inorgchem.7b01733
https://doi.org/10.1021/acs.inorgchem.7b01733
Multiple C–H Activations of Linear Alkanes by Various (η5-Cyclopentadienyl)W(NO)(CH2CMe3)2 Complexes
Autor:
Monica V. Shree, Devon C. Rosenfeld, Guillaume Lefèvre, Diana Fabulyak, Aurélien Béthegnies, Kevan E. Dettelbach, Peter Legzdins, Brian O. Patrick, Rhett A. Baillie
Publikováno v:
Organometallics. 36:2714-2726
As illustrated in the accompanying diagram, thermolysis of Cp*W(NO)(CH2CMe3)2 (Cp* = η5-C5Me5) at 80 °C in neat linear alkanes effects three successive C–H bond activations of the hydrocarbon substrates and forms Cp*W(NO)(H)(η3-allyl) complexes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::107c8302ca27d657b5b0a68202c2b0e0
https://doi.org/10.1021/acs.organomet.7b00034
https://doi.org/10.1021/acs.organomet.7b00034
Publikováno v:
Organometallics. 36:39-52
Cp*W(NO)(CH2CMe3)(η3-CH2CHCHPh) (1) effects C(sp3)–H activations of methane, ethane, propane, and n-butane exclusively at their terminal carbons and forms the corresponding Cp*W(NO)(alkyl)(η3-CH2CHCHPh) complexes. It also activates (n-Bu)2O, 1-ch
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2d3811ee02f9b1e19e0c67d36031f5dd
https://doi.org/10.1021/acs.organomet.6b00739
https://doi.org/10.1021/acs.organomet.6b00739
Publikováno v:
Organometallics. 36:26-38
Cp*W(NO)(CH2CMe3)(η3-CH2CHCMe2) (1) initiates a stepwise conversion of methane into unsymmetrical unsaturated ketones. The first step involves the activation of methane by 1 in cyclohexane to form Cp*W(NO)(CH3)(η3-CH2CHCMe2) (2) in good yield as a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::eb96d5d96eba7dcb94e01264e9c4d8b2
https://doi.org/10.1021/acs.organomet.6b00738
https://doi.org/10.1021/acs.organomet.6b00738
Autor:
Rhett A. Baillie, Peter Legzdins
Publikováno v:
Coordination Chemistry Reviews. 309:1-20
The syntheses and characteristic physical and chemical properties of representative members of important types of cyclopentadienyl nitrosyl complexes of the Group 6 elements are reviewed. These organometallic compounds contain either 14-valence-elect
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c6ef45fc64190cecdc905b1935f0d3a9
https://doi.org/10.1016/j.ccr.2015.11.003
https://doi.org/10.1016/j.ccr.2015.11.003
Publikováno v:
Organometallics. 34:4085-4092
C–H activations of a C(sp2)–H bond in benzene or a C(sp3)–H bond in mesitylene at 80 °C under CO pressure in undried solvents without rigorous exclusion of air and moisture can be effected with the 18e complexes Cp*W(NO)(H)(η3-CH2CHCMe2) (1),
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a991947979d08ec51e57edbb2fd30f1e
https://doi.org/10.1021/acs.organomet.5b00537
https://doi.org/10.1021/acs.organomet.5b00537
Publikováno v:
Inorganic chemistry. 56(20)
This article describes the differing chemical properties imparted by the two ligands, hemilabile 2-[(diisopropylphosphino)methyl]-3-methylpyridine (iPr2PN) and the related 1,2-bis(dimethylphosphino)ethane (dmpe), when attached to the 14e Cp*M(NO) sca
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c49a52b1a3944344d653569590e3dfdc
https://pubmed.ncbi.nlm.nih.gov/28976742
https://pubmed.ncbi.nlm.nih.gov/28976742
Publikováno v:
Inorganic chemistry. 56(18)
Reaction of Cp*Mo(NO)Cl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::ef4fb7047c128b93d165b781fe8a6aa2
https://pubmed.ncbi.nlm.nih.gov/28876057
https://pubmed.ncbi.nlm.nih.gov/28876057
Publikováno v:
Inorganic chemistry. 56(6)
Treatment of CH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::091297d6d7ef0d54b2607205fefc6682
https://pubmed.ncbi.nlm.nih.gov/28252956
https://pubmed.ncbi.nlm.nih.gov/28252956
Treatment of CH2Cl2 solutions of Cp*M(NO)Cl2 (Cp* = η5-C5(CH3)5; M = Mo, W) first with 2 equiv of AgSbF6 in the presence of PhCN and then with 1 equiv of Ph2PCH2CH2PPh2 affords the yellow–orange salts [Cp*M(NO)(PhCN)(κ2-Ph2PCH2CH2PPh2)](SbF6)2 in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::76dd6bfca12c7b40b4d0444ba9d6f457
https://cronfa.swan.ac.uk/Record/cronfa32716/Download/0032716-24042017112037.pdf
https://cronfa.swan.ac.uk/Record/cronfa32716/Download/0032716-24042017112037.pdf
