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pro vyhledávání: '"Peter J. F. de Rege"'
Publikováno v:
Inorganic Chemistry Communications. 1:197-199
[η5-C5H4(CH2CH2(CF2)9CF3]Rh(CO)L (L = CO (1) or P[CH2CH2(CF2)5CF3]3 (2)) and Cl2Ni{P[CH2CH2(CF2)5CF3]3}2 (3) were prepared and characterized. The fluorous partition coefficients ( P FBS = C Fluorous Phase C Other phase ) of 1 (PFBS = 0.8), 2 (PFBS =
Publikováno v:
Science (New York, N.Y.). 276(5313)
The formyl cation, HCO + , has long been believed to be an important intermediate in the chemistry of carbon monoxide (CO) in acidic environments, but its spectroscopic observation in solution has been elusive. This species was generated by the react
Publikováno v:
ResearcherID
The carbonylation of CH4 with carbon monoxide in superacids HF/SbF5 or HSO3F/SbF5 leads to the exclusive and quantitative formation of the acylium ion ([CH3CO]+[SbF6]−) with the concomitant stoichiometric formation of SbF3.
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