Zobrazeno 1 - 10
of 73
pro vyhledávání: '"Peter Gantzel"'
Publikováno v:
Inorganic Chemistry. 48:4201-4206
The ferromagnet [FeCp*(2)][TCNE] (T(c) = 4.80 K) has two structural phase transitions at 249 and 282 K that has thwarted the determination of its structure by single crystal X-ray diffraction; however, its structure at 100 K is reported [P2(1)/c, a =
Publikováno v:
Tetrahedron Letters. 47:7841-7844
The first paraquat-based [3](taco complex) was successfully prepared from a linear bis(crown ether) host and paraquat as shown by proton NMR characterization and X-ray analysis. It has a dumbbell shape in the solid state. The two crown ether binding
Publikováno v:
Polyhedron. 22:1641-1644
The synthesis of the triangular trinuclear nickel complexes ([Ni3(μ-I)2(μ-dppa)3]+n, n=0, +1; dppa=ligand bis(diphenylphosphine)amine), is reported. The crystallographic study of these clusters allows a detailed structural comparison with the bis(d
Publikováno v:
Journal of Organometallic Chemistry. 651:90-97
The reaction of S-(Ph 2 P) 2 N(CHMePh) with sulfur (1:1 molar ratio) in diethyl ether solution leads to S-Ph 2 P(S)N(CHMePh)PPh 2 ( 1 ). The disulphide S-{Ph 2 P(S)} 2 N(CHMePh) ( 2 ), was obtained when the reaction was carried out in tetrahydrofuran
Autor:
Dean M. Roddick, Kristin Hiibner, Peter Gantzel, Joseph M. O'Connor, Adam Closson, and Richard Merwin
Publikováno v:
Organometallics. 20:3710-3717
Treatment of the iridacyclopentadiene complex (1, R = CO2CH3) with silver tetrafluoroborate, followed by addition of a terminal alkyne (ethyne, ethyl ethnynyl ether, methyl propargyl ether), yields iridium(III) aryl-hydride complexes (6-H, R1 = H; 6-
Autor:
David N. Hendrickson, Ziming Sun, Peter Gantzel, Sheila M. J. Aubin, Ilia A. Guzei, Evan Rumberger, George Christou, Arnold L. Rheingold, Kirsten Folting, Hilary J. Eppley
Publikováno v:
Polyhedron. 20:1139-1145
New Mn12 single-molecule magnets (SMM's) with the composition [Mn12O12(O2CR)16(H2O)4] were prepared and structurally characterized. Complexes of this type can exhibit two out-of-phase ac magnetic susceptibility signals, one in the 4-7 K region and th
Autor:
Evan Rumberger, Sheila M. J. Aubin, Ziming Sun, Ilia A. Guzei, Kirsten Folting, Peter Gantzel, George Christou, Arnold L. Rheingold, Hilary J. Eppley, David N. Hendrickson
Publikováno v:
Inorganic Chemistry. 40:2127-2146
Several single-molecule magnets with the composition [Mn12O12(O2CR)16(H2O)x] (x = 3 or 4) exhibit two out-of-phase ac magnetic susceptibility signals, one in the 4−7 K region and the other in the 2−3 K region. New Mn12 complexes were prepared and
Publikováno v:
Organometallics. 20:1482-1485
The five-coordinate iridium metallacycle [(PPh3)2Ir(CRCRCRCR)(Cl)] (5, R = CO2CH3) and trisphosphine [PhP(CH2CH2PPh2)2] are readily converted in refluxing toluene to the fac- and mer-triphos metall...
Publikováno v:
Inorganic Chemistry. 38:3414-3422
The syntheses, crystal structures, electronic absorption spectra, electrochemical properties, and photophysical properties of a series of copper(I) bis(phenanthroline) complexes are reported. The phenanthroline ligands that have been prepared and inv
Publikováno v:
Organometallics. 18:823-831
Reaction of the titanium tetraamide Ti(NMe2)4 with various bis(sulfonamide) ligands resulted in the clean formation of the bis(sulfonamido)Ti(NMe2)2 complexes and N,N-dimethylamine. We have characterized the resulting racemic and resolved bis(sulfona