Zobrazeno 1 - 10
of 512
pro vyhledávání: '"Peter G, Bruce"'
Autor:
Boyang Liu, Shengda D. Pu, Christopher Doerrer, Dominic Spencer Jolly, Robert A. House, Dominic L. R. Melvin, Paul Adamson, Patrick S. Grant, Xiangwen Gao, Peter G. Bruce
Publikováno v:
SusMat, Vol 3, Iss 5, Pp 721-728 (2023)
Abstract Solid‐state lithium batteries may provide increased energy density and improved safety compared with Li‐ion technology. However, in a solid‐state composite cathode, mechanical degradation due to repeated cathode volume changes during c
Externí odkaz:
https://doaj.org/article/581a2e5ad40844069ea565b883150e3c
Autor:
Kit McColl, Robert A. House, Gregory J. Rees, Alexander G. Squires, Samuel W. Coles, Peter G. Bruce, Benjamin J. Morgan, M. Saiful Islam
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-8 (2022)
The oxygen-redox mechanism in lithium-rich disordered rocksalt cathode materials is still not well understood. Here, the authors show that in Li2MnO2F, molecular oxygen forms in the bulk during charge and is re-incorporated into the structure as oxyg
Externí odkaz:
https://doaj.org/article/95fdf0691c24448785591ffcfd617781
Autor:
Robert A. House, John-Joseph Marie, Joohyuk Park, Gregory J. Rees, Stefano Agrestini, Abhishek Nag, Mirian Garcia-Fernandez, Ke-Jin Zhou, Peter G. Bruce
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
In this work, authors show that O-redox in 4d and 5d transition metal oxides involves the formation of molecular oxygen trapped in the particles. These results are in accord with observations in 3d oxides and show that the greater covalency of the 4d
Externí odkaz:
https://doaj.org/article/e61d8756b723447082d259cb86fac7b4
Autor:
Xiao Hua, Phoebe K. Allan, Chen Gong, Philip A. Chater, Ella M. Schmidt, Harry S. Geddes, Alex W. Robertson, Peter G. Bruce, Andrew L. Goodwin
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
The charging of Fe and Mn oxide anodes in lithium-ion batteries are believed to form rocksalt phases via reconstructive conversion reactions. Here, the authors show that M x O y (M = Fe, Mn) transform into non-native body-centred cubic FeO and zincbl
Externí odkaz:
https://doaj.org/article/580f3f8d7a7a444bb3a1c8e85eb8051c
Autor:
Xiao Hua, Phoebe K. Allan, Harry S. Geddes, Elizabeth Castillo-Martínez, Philip A. Chater, Thomas S. Dean, Arianna Minelli, Peter G. Bruce, Andrew L. Goodwin
Publikováno v:
Cell Reports Physical Science, Vol 2, Iss 9, Pp 100543- (2021)
Summary: Binary metal oxides have received sustained interest as anode materials due to their desirable capacities, exceeding theoretical values particularly in the first discharge. Although they have received increasing attention in recent years, to
Externí odkaz:
https://doaj.org/article/68a1c464a55d40e2bb41c6ff7a1d5ae1
Autor:
Dominic Spencer-Jolly, Varnika Agarwal, Christopher Doerrer, Bingkun Hu, Shengming Zhang, Dominic L.R. Melvin, Hui Gao, Xiangwen Gao, Paul Adamson, Oxana V. Magdysyuk, Patrick S. Grant, Robert A. House, Peter G. Bruce
Publikováno v:
Joule. 7:503-514
Ag-carbon composite interlayers have been reported to enable Li-free (anodeless) cycling of solid-state batteries. Here, we report structural changes in the Ag-graphite interlayer, showing that on charge, Li intercalates electrochemically into graphi
Autor:
Dominic Spencer Jolly, Dominic L. R. Melvin, Isabella D. R. Stephens, Rowena H. Brugge, Shengda D. Pu, Junfu Bu, Ziyang Ning, Gareth O. Hartley, Paul Adamson, Patrick S. Grant, Ainara Aguadero, Peter G. Bruce
Publikováno v:
Inorganics, Vol 10, Iss 5, p 60 (2022)
Hybrid solid-state batteries using a bilayer of ceramic and solid polymer electrolytes may offer advantages over using a single type of solid electrolyte alone. However, the impedance to Li+ transport across interfaces between different electrolytes
Externí odkaz:
https://doaj.org/article/ebee9e74a1784813bd9dd86e80e2cdc3
Autor:
Robert A. House, Gregory J. Rees, Kit McColl, John-Joseph Marie, Mirian Garcia-Fernandez, Abhishek Nag, Ke-Jin Zhou, Simon Cassidy, Benjamin J. Morgan, M. Saiful Islam, Peter G. Bruce
Publikováno v:
House, R A, Rees, G J, McColl, K, Marie, J J, Garcia-Fernandez, M, Nag, A, Zhou, K J, Cassidy, S, Morgan, B J, Saiful Islam, M & Bruce, P G 2023, ' Delocalized electron holes on oxygen in a battery cathode ', Nature Energy, vol. 8, no. 4, pp. 351-360 . https://doi.org/10.1038/s41560-023-01211-0
Oxide ions in transition metal oxide cathodes can store charge at high voltage offering a route towards higher energy density batteries. However, upon charging these cathodes, the oxidized oxide ions condense to form molecular O2 trapped in the mater
Autor:
Chen Gong, Shengda D. Pu, Shengming Zhang, Yi Yuan, Ziyang Ning, Sixie Yang, Xiangwen Gao, Chloe Chau, Zixuan Li, Junliang Liu, Liquan Pi, Boyang Liu, Isaac Capone, Bingkun Hu, Dominic L. R. Melvin, Mauro Pasta, Peter G. Bruce, Alex W. Robertson
Publikováno v:
Energy & Environmental Science. 16:535-545
Ether solvent based electrolytes exhibit excellent performance with sodium battery anodes, outperforming the carbonate electrolytes that are routinely used with the analogous lithium-ion battery. Uncovering the mechanisms that facilitate this high pe
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
The kinetics of Li2O2 oxidation is of high importance to the operation of Li–O2 batteries. Here the authors work on different types of mediators revealing the dependence of the kinetics on the nature of the redox active site and its steric hindranc
Externí odkaz:
https://doaj.org/article/329737292e2247d0a17691900d0afa04