Zobrazeno 1 - 10
of 94
pro vyhledávání: '"Peter E. Yankwich"'
Autor:
Peter E. Yankwich
Publikováno v:
Yankwich, Peter E.(2010). Loss of Radioactivity from Barium Carbonate Samples. Lawrence Berkeley National Laboratory. Lawrence Berkeley National Laboratory: Lawrence Berkeley National Laboratory. Retrieved from: http://www.escholarship.org/uc/item/62c6h58k
The exchange loss of radioactivity from solid samplos of barium carbonate through the agency of carbonic acid and its ions has been investigated under a variety of conditions. It is concluded that the losses observed are greatly dependent upon the me
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d07f0f0a842cc00778823f12c7ad838
http://www.escholarship.org/uc/item/62c6h58k
http://www.escholarship.org/uc/item/62c6h58k
Publikováno v:
The Journal of Chemical Physics. 64:2868-2877
Intermolecular and intramolecular 13C kinetic isotope effects in the pyrolysis of dimethyl ether were measured at temperatures between 451 and 550 °C; initial pressures were between 14 and 1000 torr. A few experiments on the NO‐inhibited reaction
Publikováno v:
The Journal of Chemical Physics. 62:4757-4763
Intermolecular 13C kinetic isotope effects in the decomposition in dioxane solution of oxalic acid to carbon dioxide and formic acid were determined at several temperatures between 80 and 132 °C. The isotope effect is normal in sign (k12C ≳ k13C),
Autor:
Peter E. Yankwich, G.‐J. Wei
Publikováno v:
The Journal of Chemical Physics. 62:2200-2208
Calculations of the temperature dependent factor (TDF) in the isotopic ratio of specific rate constants kC12/kC13 for the decomposition of formic acid were carried out exactly and in the first order and second order high temperature approximations fo
Intramolecular 13C kinetic isotope effects in the decarboxylation of oxalic acid in dioxane solution
Publikováno v:
The Journal of Chemical Physics. 65:801-807
Autor:
Peter E. Yankwich, G.‐J. Wei
Publikováno v:
The Journal of Chemical Physics. 60:3619-3633
Effects of barrier curvature and of a restricted method for selection of values for off‐diagonal force constants in the transition state were studied by computation for several three‐element reaction coordinates assumed for decomposition of formi
Autor:
Peter E. Yankwich, Joseph H. Keller
Publikováno v:
Journal of the American Chemical Society. 96:2303-2314
Autor:
Joseph H. Keller, Peter E. Yankwich
Publikováno v:
The Journal of Physical Chemistry. 78:544-554
A study was made of the influence of curvature of the potential barrier on heavy-atom kinetic isotope effects calculated for reaction coordinates comprising nonzero displacements in three internal coordinates. Increase in barrier curvature may increa
Publikováno v:
Analytical Chemistry. 19:828-832
Publikováno v:
The Journal of Physical Chemistry. 69:918-922